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Cambridge & Pearson Edexcel Past Paper Questions

Browse 35,704 questions from Cambridge O-Level & A-Level and Pearson Edexcel IGCSE & IAL exams. Click any question to practice.

A-LevelChemistryAtoms, molecules and stoichiometryFeb/Mar 2017

In an experiment, 0.600 mol of chlorine gas, Cl₂, is reacted with an excess of hot aqueous sodium hydroxide. One of the products is NaClO₃. Which m...

A-LevelChemistryGroup 2Feb/Mar 2017

Z is an anhydrous compound of a Group 2 element. When it is heated, Z undergoes thermal decomposition to produce two different gases. Z has relativ...

A-LevelChemistryIntroduction to organic chemistryFeb/Mar 2017

Methylamine, CH₃NH₂, has very similar chemical properties to ammonia, NH₃. Methylamine reacts with hydrogen chloride to form a white crystalline sa...

A-LevelChemistryHydrocarbonsFeb/Mar 2017

Structural isomerism and stereoisomerism should be considered when answering this question. How many isomers with the formula C₄H₈ have structures ...

A-LevelChemistryHydrocarbonsFeb/Mar 2017

Kerosene is used as an aircraft fuel. Q is one of the molecules in kerosene and has the skeletal formula shown. [Figure showing skeletal formula of...

A-LevelChemistryHalogen derivativesFeb/Mar 2017

Which radical is most likely to form by the homolytic fission of one covalent bond in bromochloromethane, CH₂BrCl?

A-LevelChemistryHydrocarbonsFeb/Mar 2017

Propene undergoes a variety of reactions. Which row is correct?

A-LevelChemistryPolymerisationFeb/Mar 2017

Polymerisation of ethene gives poly(ethene). How does the bonding between carbon atoms in poly(ethene) compare with that in ethene?

A-LevelChemistryCarbonyl compoundsFeb/Mar 2017

Diols in which both hydroxy groups are bonded to the same carbon can spontaneously eliminate a molecule of water to produce a carbonyl compound. Wh...

A-LevelChemistryHydroxy compoundsFeb/Mar 2017

Propan-2-ol undergoes many reactions. Which row is correct?

A-LevelChemistryHydroxy compoundsFeb/Mar 2017

Ethane-1,2-diol has the following structure. [Figure showing HO-CH₂-CH₂-OH]. Without breaking the C-C bond, there are five possible oxidation produ...

A-LevelChemistryCarbonyl compoundsFeb/Mar 2017

CH₃CH₂COCH₂CH₃ reacts with hydrogen cyanide to form an organic product called a cyanohydrin. Which statement is correct?

A-LevelChemistryCarbonyl compoundsFeb/Mar 2017

Compound X, CH₃CH(OH)CH(CHO)CH₃, is heated under reflux with an excess of acidified K₂Cr₂O₇ to form compound Y. Both X and Y are separately warmed ...

A-LevelChemistryCarboxylic acids and derivativesFeb/Mar 2017

Which two compounds can react together to produce an ester?

A-LevelChemistryChemical bondingFeb/Mar 2017

Nitrogen and phosphorus are both in Group 15 of the Periodic Table. Phosphorus forms a chloride with the formula PCl₅ but nitrogen does not form NC...

A-LevelChemistryStates of matterFeb/Mar 2017

When a sample of a gas is compressed at constant temperature from 1500 kPa to 6000 kPa, its volume changes from 76.0 cm³ to 20.5 cm³. Which stateme...

A-LevelChemistryAtoms, molecules and stoichiometryFeb/Mar 2017

Which of these statements are always correct? 1 The sum of the oxidation numbers of all the atoms in a compound is zero. 2 The oxidation number of ...

A-LevelChemistryEquilibriaFeb/Mar 2017

Sulfur dioxide and oxygen react in the gas phase. 2SO₂(g) + O₂(g) ⇌ 2SO₃(g) ∆H = –197 kJ mol⁻¹ Which statements are correct? 1 Increasing the press...

A-LevelChemistryChemical periodicityFeb/Mar 2017

Three test-tubes, X, Y, and Z, each contain a small amount of water. • A small amount of NaCl is added to test-tube X. • A small amount of SiCl₄ is...

A-LevelChemistryGroup 17Feb/Mar 2017

Sodium chloride and sodium iodide react with concentrated sulfuric acid. Which statements are correct? 1 Sodium chloride is not oxidised by concent...

A-LevelChemistryHydrocarbonsFeb/Mar 2017

Which compounds can be obtained from but-2-ene in a single reaction? 1 CH₃CH(OH)CH(OH)CH₃ 2 CH₃CH(OH)CH₂CH₃ 3 CH₃CO₂H

A-LevelChemistryHalogen derivativesFeb/Mar 2017

Which statements help to explain the mechanism of the reaction between 1-chloropropane and ammonia? 1 1-chloropropane has a δ− chlorine atom that f...

A-LevelChemistryAnalytical techniquesFeb/Mar 2017

Which compounds react with alkaline aqueous iodine to give a pale yellow precipitate of tri-iodomethane? 1 butanone 2 ethanal 3 propan-2-ol

A-LevelChemistryOrganic synthesisFeb/Mar 2017

Propanoic acid occurs naturally as a result of the bacterial fermentation of milk and is partly responsible for the flavour of Swiss cheese. [Figur...

A-LevelChemistryChemical periodicityFeb/Mar 2017

(a) The table shows information about some of the elements in the third period. element | Na | Mg | Al | P | S | Cl ---|---|---|---|---|---|--- at...

A-LevelChemistryChemical bondingFeb/Mar 2017

Hydrogen halides are compounds formed when halogens (Group 17 elements) react with hydrogen. The bond polarity of the hydrogen halides decreases fr...

A-LevelChemistryOrganic synthesisFeb/Mar 2017

(a) A series of reactions starting from 1-bromobutane is shown. [Figure showing reaction scheme: 1-bromobutane reacts with HCN and KCN to form P, t...

A-LevelChemistryAtoms, molecules and stoichiometryFeb/Mar 2017

The concentration of hydrogen peroxide may be given in moldm-³ or as 'volume strength'. You will determine the concentration of hydrogen peroxide i...

A-LevelChemistryAtoms, molecules and stoichiometryFeb/Mar 2017

You will carry out a second experiment to determine the concentration of hydrogen peroxide, FA 1, in moldm⁻³, by titration with acidified aqueous p...

A-LevelChemistryAnalytical techniquesFeb/Mar 2017

Qualitative Analysis At each stage of any test you are to record details of the following. • colour changes seen • the formation of any precipitate...

A-LevelChemistryAtoms, molecules and stoichiometryFeb/Mar 2017

The mass spectrum of silicon is shown. [Diagram: A mass spectrum showing relative intensity on the y-axis (up to 1.0) and m/e on the x-axis (from 2...

A-LevelChemistryChemical energeticsFeb/Mar 2017

Complete the table using ticks (√) to indicate whether the sign of each type of energy change, under standard conditions, is always positive, alway...

A-LevelChemistryElectrochemistryFeb/Mar 2017

(a) The diagram shows the apparatus used to measure the standard electrode potential, E°, of Fe³⁺(aq)/Fe²⁺(aq). [Figure showing apparatus for stand...

A-LevelChemistryReaction kineticsFeb/Mar 2017

(a) Chlorine dioxide undergoes the following reaction in aqueous solution. 2ClO₂ + 2OH⁻ → ClO₂⁻ + ClO₃⁻ + H₂O The initial rate of the reaction was ...

A-LevelChemistryOrganic synthesisFeb/Mar 2017

(a) Compound H can be synthesised from benzene as shown. [Figure: Reaction scheme starting from benzene, going through step 1, then intermediate G,...

A-LevelChemistryChemical periodicityFeb/Mar 2017

(a) (i) Draw the shape of one of the d orbitals.

A-LevelChemistryIntroduction to organic chemistryFeb/Mar 2017

The compound Advantame is a sweetener that tastes approximately 25000 times sweeter than sucrose. [Figure: Structure of Advantame (C23H29NO4)]

A-LevelChemistryHydroxy compoundsFeb/Mar 2017

The root of the ginger plant contains compounds with medicinal and flavouring properties. Three of the more important compounds are gingerol, shoga...

A-LevelChemistryAnalytical techniquesFeb/Mar 2017

This question is about compound T, CₓH_yO₂. (a) Part of the mass spectrum of T is shown. The peak heights of the M and M+1 peaks are 33.9 and 3.4 r...

A-LevelChemistryChemical energeticsFeb/Mar 2017

The enthalpy change of reaction, ∆H, for the decomposition of sodium hydrogencarbonate, NaHCO3(s), cannot be measured directly. 2NaHCO3(s) → Na2CO3...

A-LevelChemistryAnalytical techniquesFeb/Mar 2017

Transition metal complex ions are coloured. The formula of a complex ion can be determined using colorimetry. In colorimetry, light of a certain wa...

A-LevelChemistryChemical bondingFeb/Mar 2018

What are the shapes of the molecules of water and boron trifluoride?

A-LevelChemistryAtomic structureFeb/Mar 2018

The electronic configuration of the two outermost shells of an atom is 3s²3p³3d⁵4s². What is this atom?

A-LevelChemistryAtoms, molecules and stoichiometryFeb/Mar 2018

Drinking water may contain dissolved calcium hydrogencarbonate, Ca(HCO₃)₂. How many electrons are present in a hydrogencarbonate anion?

A-LevelChemistryChemical bondingFeb/Mar 2018

Which molecule contains a nitrogen atom with sp hybridised orbitals?

A-LevelChemistryAtoms, molecules and stoichiometryFeb/Mar 2018

Which mass of solid residue is obtained from the thermal decomposition of 4.10 g of anhydrous calcium nitrate?

A-LevelChemistryAtoms, molecules and stoichiometryFeb/Mar 2018

Sodium hydroxide neutralises acid. H⁺ + OH⁻ → H₂O In a 11000 dm³ sample of an aqueous solution, the concentration of acid, [H⁺], is 1.26 x 10⁻³ mol...

A-LevelChemistryStates of matterFeb/Mar 2018

The gas laws can be summarised in the ideal gas equation. pV = nRT 0.960 g of oxygen gas is contained in a vessel of volume 7.00 × 10⁻³ m³ at a tem...

A-LevelChemistryChemical energeticsFeb/Mar 2018

Which equation represents the standard enthalpy change of formation of water?

A-LevelChemistryChemical energeticsFeb/Mar 2018

Hess' Law and bond energy data can be used to calculate the enthalpy change of a reaction. Bromoethane, CH₃CH₂Br, can be made by reacting ethene wi...

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