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Cambridge Past Paper Questions

Browse 23,045questions from 25 years of O-Level & A-Level exams. Click any question to practice.

A-LevelChemistryIntroduction to organic chemistryMay/June 2017

P, Q and R all have the molecular formula C₃H₆O. They are all structural isomers of each other. P and Q each contain an oxygen atom bonded directly...

A-LevelChemistryAtomic structureMay/June 2017

The composition of atoms and ions can be determined from knowledge of atomic number, nucleon number and charge.

A-LevelChemistryNitrogen and sulfurMay/June 2017

Nitrogen gas, N₂, is very unreactive.

A-LevelChemistryReaction kineticsMay/June 2017

The hydrogen halides, HCl, HBr and HI, can undergo thermal decomposition. In a sealed container an equilibrium is established according to the equa...

A-LevelChemistryHydrocarbonsMay/June 2017

A-LevelChemistryGroup 17May/June 2017

The halogens, chlorine, bromine and iodine, and their compounds, show a variety of similarities and trends in their physical and chemical properties.

A-LevelChemistryChemical energeticsMay/June 2017

Sulfur trioxide, SO3, is manufactured from sulfur dioxide and oxygen by the Contact process. 2SO2(g) + O2(g) ⇌ 2SO3(g) ΔH = –196.0 kJ mol⁻¹

A-LevelChemistryHydrocarbonsMay/June 2017

A, B and C all have the formula C₄H₈. They all decolourise bromine and are structural isomers of each other.

A-LevelChemistryAnalytical techniquesMay/June 2017

In this experiment you will determine the relative formula mass of a copper salt by titration. A solution of the copper salt reacts with excess aci...

A-LevelChemistryAnalytical techniquesMay/June 2017

Malachite is a basic form of copper carbonate in which copper hydroxide is also present. The accepted chemical formula of malachite is CuCO3.Cu(OH)...

A-LevelChemistryAnalytical techniquesMay/June 2017

HA is an organic acid where A¯ is the anion. You will determine the relative formula mass, M., of HA by titration with sodium hydroxide of known co...

A-LevelChemistryChemical energeticsMay/June 2017

You are to determine the enthalpy change of neutralisation for a different acid from that used in Question 1. The acid is represented by HB where B...

A-LevelChemistryAnalytical techniquesMay/June 2017

Sodium hydrogencarbonate, NaHCO3, is used as baking soda in cooking. Baking soda may also contain small amounts of other chemicals. In this experim...

A-LevelChemistryAnalytical techniquesMay/June 2017

When baking soda is heated, carbon dioxide is produced. In this experiment you will investigate the reaction taking place when the sodium hydrogenc...

A-LevelChemistryGroup 2May/June 2017

The table lists the standard enthalpy changes of formation, ΔΗ, for some compounds and aqueous ions. ``` species ΔH_f/kJ mol⁻¹ Ba²⁺(aq) ...

A-LevelChemistryChemical bondingMay/June 2017

One atom of each of the four elements H, C, N and O can bond together in different ways. Two examples are molecules of cyanic acid, HOCN, and isocy...

A-LevelChemistryChemical periodicityMay/June 2017

Bubbling air through different aqueous mixtures of CoCl₂, NH₄Cl and NH₃ produces various complex ions with the general formula [Co(NH₃)₆₋nClₙ]³⁻ⁿ.

A-LevelChemistryOrganic synthesisMay/June 2017

Carvone occurs in spearmint and a stereoisomer of carvone occurs in caraway seeds. Treating either isomer with hydrogen over a nickel catalyst prod...

A-LevelChemistryOrganic synthesisMay/June 2017

Compounds J, K, L and M are isomers of each other with the molecular formula C₉H₁₁NO. All four isomers contain a benzene ring. Two of the isomers c...

A-LevelChemistryReaction kineticsMay/June 2017

The reaction between 1-chloro-1-phenylethane and hydroxide ions to produce 1-phenylethanol is: C₆H₅CH(Cl)CH₃ + OH⁻ → C₆H₅CH(OH)CH₃ + Cl⁻ 1-chloro-1...

A-LevelChemistryGroup 2May/June 2017

A-LevelChemistryHalogen derivativesMay/June 2017

A-LevelChemistryAtoms, molecules and stoichiometryMay/June 2017

A-LevelChemistryChemical bondingMay/June 2017

A number of isomers with the formula Cr(H2O)6Cl3 exist. Their general formula is [Cr(H2O)6-nCln]Cl3-n.nH2O. Each isomer contains a six co-ordinated...

A-LevelChemistryChemical bondingMay/June 2017

1,2-diaminoethane, en, H2NCH2CH2NH2, is a bidentate ligand.

A-LevelChemistryEquilibriaMay/June 2017

The table lists some organic acids and their pKa values. acid formula pKa ethanoic acid CH3CO₂H 4.76 chloroethanoic acid CICH₂CO₂H 2.86 aminoet...

A-LevelChemistryAnalytical techniquesMay/June 2017

Compounds W, X, Y and Z are isomers of each other with the molecular formula C。H,CIO. All four isomers contain a benzene ring. Only one of the isom...

A-LevelChemistryOrganic synthesisMay/June 2017

The amino acid tyrosine can be synthesised from phenol by the route shown. OH step 1 CHO step 2 CN HO HO phenol HO step 3 NH2 Cl OH step 5 s...

A-LevelChemistryGroup 2May/June 2017

The table lists the standard enthalpy changes of formation, ΔH, for some compounds and aqueous ions. | species | ΔHᶠ/kJ mol⁻¹ | |------------|-...

A-LevelChemistryChemical energeticsMay/June 2017

The pain of muscle strains and swellings can be eased by using heat packs. As a source of heat, some heat packs use the energy released when anhydr...

A-LevelChemistryAnalytical techniquesMay/June 2017

Sucrose is a sugar. The concentration of a solution of sucrose can be measured by the optical rotation, α, of a sucrose solution. The more concentr...

A-LevelChemistryAnalytical techniquesMay/June 2017

In 1804 the chemist John Dalton put forward the following idea. It is sometimes called 'Dalton's Law'. 'When two elements combine with each other ...

A-LevelChemistryAnalytical techniquesMay/June 2017

When light passes through solutions of chemical compounds some of the light may be absorbed. The quantity of light absorbed is called the absorbanc...

A-LevelChemistryChemical bondingMay/June 2018

Which feature is present in both ethene and poly(ethene)?

A-LevelChemistryAtomic structureMay/June 2018

The electronic configuration of an atom of sulfur is 1s²2s²2p⁶3s²3p⁴. How many valence shell and unpaired electrons are present in one sulfur atom?...

A-LevelChemistryStates of matterMay/June 2018

In which pair does the second substance have a lower boiling point than the first substance?

A-LevelChemistryAtoms, molecules and stoichiometryMay/June 2018

Compound J burns in excess oxygen to give carbon dioxide and water only. When a 3.00 g sample of compound J is burnt in excess oxygen, 4.40 g of ca...

A-LevelChemistryEquilibriaMay/June 2018

The gases X and Y react to form Z. X(g) + Y(g) ⇌ Z(g) An equilibrium mixture of these three gases is compressed at constant temperature. What will ...

A-LevelChemistryStates of matterMay/June 2018

Which gas is likely to deviate most from ideal gas behaviour?

A-LevelChemistryChemical energeticsMay/June 2018

The enthalpy change of reaction 1 is –114 kJ mol⁻¹. 2NaOH(aq) + H2SO4(aq) → Na2SO4(aq) + 2H2O(l) reaction 1 By using this information, what is the ...

A-LevelChemistryElectrochemistryMay/June 2018

Sulfur reacts with concentrated nitric acid in a redox reaction. S + 4HNO3 → SO2 + 4NO2 + 2H2O What are the changes in oxidation number of sulfur a...

A-LevelChemistryChemical bondingMay/June 2018

Materials can be classified by their chemical structures. Four common types of structure are metallic, ionic, simple molecular and giant molecular....

A-LevelChemistryEquilibriaMay/June 2018

In a particular reversible reaction the yield of product is increased • if the temperature is increased; • if the pressure is decreased. Which equa...

A-LevelChemistryReaction kineticsMay/June 2018

A chemical company used a catalyst in a chemical process. The company has now decided not to use the catalyst but to increase the temperature so th...

A-LevelChemistryChemical periodicityMay/June 2018

Which oxide does not react with cold, dilute sodium hydroxide to produce a salt?

A-LevelChemistryChemical periodicityMay/June 2018

The graphs show trends in four physical properties of elements in Period 3, excluding argon. Which graph has electronegativity on the y-axis? [Grap...

A-LevelChemistryGroup 17May/June 2018

In this question, X represents an atom of chlorine, bromine or iodine. Which explanation for the variation in volatility down Group 17 is correct?

A-LevelChemistryAtoms, molecules and stoichiometryMay/June 2018

To manufacture cement, 1000 million tonnes of limestone are decomposed each year. To manufacture lime for agriculture, 200 million tonnes of limest...

A-LevelChemistryGroup 17May/June 2018

When concentrated sulfuric acid is added to solid sodium bromide, bromine gas is produced, along with a number of other products. However when conc...

A-LevelChemistryChemical bondingMay/June 2018

The dative covalent bond can be represented by an arrow, →. The arrow points towards the atom receiving the lone pair. Which diagram of an ammonium...

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