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Cambridge & Pearson Edexcel Past Paper Questions

Browse 35,704 questions from Cambridge O-Level & A-Level and Pearson Edexcel IGCSE & IAL exams. Click any question to practice.

A-LevelChemistryAtoms, molecules and stoichiometryMay/June 2017

A chemist took 2.00 dm³ of nitrogen gas, measured under room conditions, and reacted it with a large volume of hydrogen gas to produce ammonia. Onl...

A-LevelChemistryCarbonyl compoundsMay/June 2017

A carbonyl compound X will react with HCN in the presence of NaCN to make a compound with Mr 85. Compound X does not react with Fehling's reagent. ...

A-LevelChemistryIntroduction to organic chemistryMay/June 2017

Geraniol and linalool are compounds found in some flower fragrances. [Figure 21.1] Which statement is correct?

A-LevelChemistryHydrocarbonsMay/June 2017

Which equation represents the initiation step of the substitution reaction between methane and chlorine?

A-LevelChemistryHalogen derivativesMay/June 2017

Aqueous sodium hydroxide reacts with 1-bromopropane to give propan-1-ol. What should be included in a diagram of the first step in the mechanism?

A-LevelChemistryHydroxy compoundsMay/June 2017

A sample of 2.76 g of ethanol was mixed with an excess of aqueous acidified potassium dichromate(VI). The reaction mixture was then boiled under re...

A-LevelChemistryHydroxy compoundsMay/June 2017

Compound X is a single, pure, optical isomer. X is heated with an excess of concentrated H₂SO₄. Only one organic product is formed. What could X be?

A-LevelChemistryHalogen derivativesMay/June 2017

2-bromo-2-methylpropane undergoes nucleophilic substitution when heated under reflux with an aqueous solution of sodium hydroxide. Which row is cor...

A-LevelChemistryCarbonyl compoundsMay/June 2017

H₂NNHC₆H₃(NO₂)₂ is the structural formula of 2,4-DNPH. Many, but not all, organic reactions need to be heated before reaction occurs. Which reactio...

A-LevelChemistryCarboxylic acids and derivativesMay/June 2017

A carboxylic acid, P, has no possible chain isomers. It reacts with an alcohol, Q, that has only one positional isomer. What could be the ester for...

A-LevelChemistryCarboxylic acids and derivativesMay/June 2017

Which compound is chiral and reacts with Na₂CO₃ to give CO₂?

A-LevelChemistryCarboxylic acids and derivativesMay/June 2017

Which compound, when hydrolysed, gives propanoic acid and propan-2-ol?

A-LevelChemistryAtomic structureMay/June 2017

An isolated gaseous atom of element X has paired electrons in at least one of its 3d orbitals and has a filled 4s subshell. What could be the ident...

A-LevelChemistryChemical bondingMay/June 2017

Which allotropes of carbon have a giant molecular structure? 1 buckminsterfullerene 2 diamond 3 graphite

A-LevelChemistryChemical energeticsMay/June 2017

Which statements about endothermic reactions are correct? 1 On the reaction pathway diagram the products of the reaction are lower than the reactan...

A-LevelChemistryReaction kineticsMay/June 2017

The rate of chemical reactions can be increased by the addition of a suitable catalyst. For which reactions can a heterogeneous catalyst be used? 1...

A-LevelChemistryChemical periodicityMay/June 2017

Which chlorides, when added to water, can produce a solution with a pH of less than 5? 1 SiCl₄ 2 AlCl₃ 3 MgCl₂

A-LevelChemistryNitrogen and sulfurMay/June 2017

Acid rain continues to be a problem. Which statements about acid rain are correct? 1 Acid rain is formed when oxides of nitrogen or oxides of sulfu...

A-LevelChemistryIntroduction to organic chemistryMay/June 2017

Which compounds contain a chiral centre? 1 2-hydroxybutanoic acid 2 3-hydroxybutanoic acid 3 4-hydroxybutanoic acid

A-LevelChemistryPolymerisationMay/June 2017

The diagram shows the monomer used to make polyvinyl chloride, PVC. [Figure 38.1] Assuming that one particular molecule of the polymer forms from n...

A-LevelChemistryHydroxy compoundsMay/June 2017

An organic compound, X, has the following skeletal formula. [Figure 39.1] Which statements about X are correct? 1 X is a primary alcohol. 2 X will ...

A-LevelChemistryCarbonyl compoundsMay/June 2017

2,2,4-trimethylpentanal is used in the manufacture of adhesives. Which reagents would 2,2,4-trimethylpentanal react with? 1 2,4-dinitrophenylhydraz...

A-LevelChemistryAtoms, molecules and stoichiometryMay/June 2017

Combustion data can be used to calculate the empirical formula, molecular formula and relative molecular mass of many organic compounds.

A-LevelChemistryChemical bondingMay/June 2017

Structure and bonding can be used to explain many of the properties of substances.

A-LevelChemistryChemical periodicityMay/June 2017

The properties of elements and their compounds show similarities, differences and trends depending on the positions of the elements in the Periodic...

A-LevelChemistryIntroduction to organic chemistryMay/June 2017

P, Q and R all have the molecular formula C₃H₆O. They are all structural isomers of each other. P and Q each contain an oxygen atom bonded directly...

A-LevelChemistryAtomic structureMay/June 2017

The composition of atoms and ions can be determined from knowledge of atomic number, nucleon number and charge.

A-LevelChemistryNitrogen and sulfurMay/June 2017

Nitrogen gas, N₂, is very unreactive.

A-LevelChemistryReaction kineticsMay/June 2017

The hydrogen halides, HCl, HBr and HI, can undergo thermal decomposition. In a sealed container an equilibrium is established according to the equa...

A-LevelChemistryHydrocarbonsMay/June 2017

Draw the skeletal formula of A.

A-LevelChemistryGroup 17May/June 2017

The halogens, chlorine, bromine and iodine, and their compounds, show a variety of similarities and trends in their physical and chemical properties.

A-LevelChemistryChemical energeticsMay/June 2017

Sulfur trioxide, SO3, is manufactured from sulfur dioxide and oxygen by the Contact process. 2SO2(g) + O2(g) ⇌ 2SO3(g) ΔH = –196.0 kJ mol⁻¹

A-LevelChemistryHydrocarbonsMay/June 2017

A, B and C all have the formula C₄H₈. They all decolourise bromine and are structural isomers of each other.

A-LevelChemistryAnalytical techniquesMay/June 2017

In this experiment you will determine the relative formula mass of a copper salt by titration. A solution of the copper salt reacts with excess aci...

A-LevelChemistryAnalytical techniquesMay/June 2017

Malachite is a basic form of copper carbonate in which copper hydroxide is also present. The accepted chemical formula of malachite is CuCO3.Cu(OH)...

A-LevelChemistryAnalytical techniquesMay/June 2017

HA is an organic acid where A¯ is the anion. You will determine the relative formula mass, M., of HA by titration with sodium hydroxide of known co...

A-LevelChemistryChemical energeticsMay/June 2017

You are to determine the enthalpy change of neutralisation for a different acid from that used in Question 1. The acid is represented by HB where B...

A-LevelChemistryAnalytical techniquesMay/June 2017

Sodium hydrogencarbonate, NaHCO3, is used as baking soda in cooking. Baking soda may also contain small amounts of other chemicals. In this experim...

A-LevelChemistryAnalytical techniquesMay/June 2017

When baking soda is heated, carbon dioxide is produced. In this experiment you will investigate the reaction taking place when the sodium hydrogenc...

A-LevelChemistryGroup 2May/June 2017

The table lists the standard enthalpy changes of formation, ΔΗ, for some compounds and aqueous ions. ``` species ΔH_f/kJ mol⁻¹ Ba²⁺(aq) ...

A-LevelChemistryChemical bondingMay/June 2017

One atom of each of the four elements H, C, N and O can bond together in different ways. Two examples are molecules of cyanic acid, HOCN, and isocy...

A-LevelChemistryChemical periodicityMay/June 2017

Bubbling air through different aqueous mixtures of CoCl₂, NH₄Cl and NH₃ produces various complex ions with the general formula [Co(NH₃)₆₋nClₙ]³⁻ⁿ.

A-LevelChemistryOrganic synthesisMay/June 2017

Carvone occurs in spearmint and a stereoisomer of carvone occurs in caraway seeds. Treating either isomer with hydrogen over a nickel catalyst prod...

A-LevelChemistryOrganic synthesisMay/June 2017

Compounds J, K, L and M are isomers of each other with the molecular formula C₉H₁₁NO. All four isomers contain a benzene ring. Two of the isomers c...

A-LevelChemistryReaction kineticsMay/June 2017

The reaction between 1-chloro-1-phenylethane and hydroxide ions to produce 1-phenylethanol is: C₆H₅CH(Cl)CH₃ + OH⁻ → C₆H₅CH(OH)CH₃ + Cl⁻ 1-chloro-1...

A-LevelChemistryGroup 2May/June 2017

Describe and explain the variation in the thermal stabilities of the carbonates of the Group 2 elements.

A-LevelChemistryHalogen derivativesMay/June 2017

Complete the table to show how both AgNO3(aq) and NH3(aq) could be used to distinguish between solutions of NaCl(aq) and Nal(aq). test performed o...

A-LevelChemistryAtoms, molecules and stoichiometryMay/June 2017

In a molecule of SOCl2 the sulfur atom has four bonds. Draw a 'dot-and-cross' diagram of SOCl2. Show the outer shell electrons only.

A-LevelChemistryChemical bondingMay/June 2017

A number of isomers with the formula Cr(H2O)6Cl3 exist. Their general formula is [Cr(H2O)6-nCln]Cl3-n.nH2O. Each isomer contains a six co-ordinated...

A-LevelChemistryChemical bondingMay/June 2017

1,2-diaminoethane, en, H2NCH2CH2NH2, is a bidentate ligand.

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