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O-LevelChemistryBonding & Structure5070/22 · Oct/Nov 2018 · Q610 Marks

Some properties of Group VI elements are shown. [Figure 6.1: Table showing density at room temperature (in g/cm³), melting point (°C), boiling point (°C), and electrical conductivity of solid for oxygen, sulfur, selenium, tellurium, and polonium. Density for selenium is blank.]

  1. (a)(i)Use the information in the table to suggest the density of selenium at room temperature.[1]
  2. (a)(ii)Use the information in the table to deduce the physical state of oxygen at -190°C. Explain your answer. physical state .......... explanation ..........[2]
  3. (b)(i)Describe the trend in the electrical conductivity of the Group VI elements.[1]
  4. (b)(ii)There is a trend in the melting points of the Group VI elements. Which element does not follow this trend? Use the data in the table to explain your answer. element .......... explanation ..........[1]
  5. (c)Use the information in the table to explain how the structure and bonding in oxygen differs from the structure and bonding in polonium.[2]
  6. (d)Sulfur dioxide is an atmospheric pollutant.
  7. (d)(i)State one source of the sulfur dioxide in the atmosphere.[1]
  8. (d)(ii)Describe and explain how sulfur dioxide contributes to acid rain.[2]

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Mark scheme

Marking points from the official mark scheme (Oct/Nov 2018). The mark or mark type is shown in brackets.

  1. [1] (a)(i) 2.3 to 6.0 (inclusive)
  2. [1] (a)(ii) liquid (1)
  3. [1] (a)(ii) -190 °C is between the boiling and melting points / this temperature is higher than the melting point but lower than the boiling point (1)
  4. [1] (b)(i) increases down the group
  5. [1] (b)(ii) polonium because its melting point is lower than expected / polonium because its melting point is lower than tellurium / the melting point of the element increases down the group except for polonium
  6. [1] (c) oxygen is a (simple) molecule / oxygen has weak forces between molecules / simple covalent (structure) (1)
  7. [1] (c) polonium has metallic bonding / polonium has metallic structure (1)
  8. [1] (d)(i) burning fossil fuels (containing sulfur) / volcanoes
  9. [2] (d)(ii) sulfur dioxide reacts with oxygen AND rain / sulfur dioxide reacts with oxygen to form sulfur trioxide AND sulfur trioxide reacts with rain / sulfur dioxide reacts with water to form sulfurous acid AND sulfurous acid oxidised by oxygen (2)
  10. [1] (d)(ii) if two marks not scored 1 mark for: sulfur dioxide reacts with rain / sulfur dioxide reacts with water / sulfur dioxide forms sulfurous acid (in the atmosphere) (1)

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About this question

Topic
Bonding & Structure, O-Level Chemistry (syllabus 5070). Structured question, 10 marks.
Source
O-Level Chemistry, Oct/Nov 2018 Paper 2 Variant 2, question 6.

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