Group 2 elements share common chemical properties.
- (a)(i)Calcium reacts in cold water more quickly than magnesium because more energy is required to remove the outer electrons in magnesium. This occurs even though calcium atoms have a greater nuclear charge. Explain why more energy is required to remove the outer electrons in magnesium than in calcium.[2]
- (a)(ii)0.001 mol of strontium reacts with an excess of cold water. When the reaction is complete a colourless solution is seen. Construct the equation for the reaction of strontium with cold water. Include state symbols.[2]
- (a)(iii)0.005 mol of calcium and 0.005 mol of strontium are added separately to two beakers. Each beaker contains 100 cm³ of cold water. At the end of each reaction a white solid and a colourless solution are seen in both beakers. Predict which element, calcium or strontium, produces the more alkaline solution. Explain your answer.[2]
- (a)(iv)Describe one observation when magnesium carbonate is added to excess dilute sulfuric acid.[1]
- (b)(i)From the information given, state two similarities and one difference that metal X and its compounds have with Group 2 metals and their compounds.[3]
- (b)(ii)Write the formula of the oxide of X.[1]
- (b)(iii)Write an equation for the reaction of XCO3 when it is heated.[1]
Mark scheme
Marking points from the official mark scheme (May/June 2019). The mark or mark type is shown in brackets.
- [1] M1 (one) fewer (inner) shell of electrons / less shielding (effect) ORA
- [1] M2 smaller distance of the outer electrons (from the nucleus) / stronger nuclear attraction to the (outer) electrons ORA
- [1] M1 species AND balancing
- [1] M2 state symbols
- [1] M1 strontium AND forms a more soluble hydroxide
- [1] M2 strontium hydroxide is a stronger base / produces more OH- / it dissociates more
- [1] (white) solid dissolves / effervescence
- [1] (both have) +2 ion / (+2) same oxidation state
- [1] (both have) same stoichiometry of oxide / carbonates decompose (on heating)
- [1] (X) forms coloured compounds/oxides/ carbonates OR Group 2 elements form white compounds/oxides/carbonates
- [1] XO
- [1] XCO3 → XO + CO2
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