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A-LevelChemistryChemical periodicity9701/22 · Feb/Mar 2022 · Q19 Marks

Fig. 1.1 shows how first ionisation energies vary across Period 2. [Figure 1.1]

  1. (a)Construct an equation to represent the first ionisation energy of oxygen. Include state symbols.[1]
  2. (b)(i)State and explain the general trend in first ionisation energies across Period 2.[3]
  3. (b)(ii)Explain why ionisation energy A in Fig. 1.1 does not follow the general trend in first ionisation energies across Period 2.[2]
  4. (c)Element E is in Period 3 of the Periodic Table. The first eight ionisation energy values of E are shown in Table 1.1. Table 1.1 ionisation 1st 2nd 3rd 4th 5th 6th 7th 8th ionisation energy/kJmol⁻¹ 577 1820 2740 11600 14800 18400 23400 27500 Deduce the full electronic configuration of E. Explain your answer. full electronic configuration of E = explanation[3]

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Mark scheme

Marking points from the official mark scheme (Feb/Mar 2022). The mark or mark type is shown in brackets.

  1. [1] O(g) → O⁺(g) + e⁻
  2. [1] increase across period AND increased nuclear attraction for (valence / outer) electrons
  3. [1] increase in (positive) nuclear charge / number of protons (in the nucleus)
  4. [1] similar shielding (of outer electrons)
  5. [1] spin-pair repulsion (of electrons) in (2)p orbital
  6. [1] outweighs increased nuclear charge
  7. [1] 1s² 2s² 2p⁶ 3s² 3p¹
  8. [1] greatest jump between 3rd and 4th ionisations
  9. [1] indicates three electrons in outer shell

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About this question

Topic
Chemical periodicity, A-Level Chemistry (syllabus 9701). Structured question, 9 marks.
Source
A-Level Chemistry, Feb/Mar 2022 Paper 2 Variant 2, question 1.

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