Chlorine is one of the elements in Group 17 of the Periodic Table.
- (a)(i)Describe the colours of the Group 17 elements, chlorine to iodine, at room temperature.[1]
- (a)(ii)Describe the relative reactivity of the elements chlorine to iodine as oxidising agents.[1]
- (a)(iii)State what is observed when chlorine reacts with hydrogen.[1]
- (a)(iv)Explain why the thermal stability of the hydrogen halides decreases down the group.[1]
- (b)(i)Define free radical.[1]
- (b)(ii)State the essential condition for chlorine to react with C₂H₆ at room temperature.[1]
- (b)(iii)Write two equations to show the propagation steps in this reaction. 1 2[2]
- (c)(i)Identify a reagent and conditions that can be used to convert chlorine to NaClO.[1]
- (c)(ii)Define disproportionation.[1]
- (c)(iii)Write numbers in the boxes to balance the equation showing the reaction of propanone with NaClO. CH₃COCH₃ + ☐ NaClO → CHCl₃ + CH₃COONa + ☐ NaOH[1]
- (c)(iv)Aqueous AgNO₃ dissolved in ethanol reacts with an aqueous solution of CHCl₃. State what is observed in this reaction. Explain your answer.[2]
Mark scheme
Marking points from the official mark scheme (Oct/Nov 2024). The mark or mark type is shown in brackets.
- [1] chlorine = yellow-green; bromine = orange / brown / red; iodine = silver grey / black
- [1] oxidising strength decreases from chlorine to iodine
- [1] green colour disappears
- [1] H–Hal covalent bond strength decreases down the group
- [1] a species with one or more unpaired electrons
- [1] ultraviolet
- [1] C₂H₆ + Cl• → C₂H₅• + HCl
- [1] C₂H₅• + Cl₂ → C₂H₅Cl + Cl•
- [1] cold NaOH(aq)
- [1] a reaction where a species / same species is both oxidised and reduced simultaneously / in the same reaction
- [1] CH₃COCH₃ + 3NaCIO → 1CHCl₃ + 1CH₃COONa + 2NaOH
- [1] M1 white precipitate/white ppt forms
- [1] M2 CHCl₃ is hydrolysed / chloride ions are released OR Cl⁻ / chloride ions which are released react with Ag⁺ OR silver chloride / AgCl is formed
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