Skip to main content
A-LevelChemistryGroup 179701/21 · Oct/Nov 2024 · Q213 Marks

Chlorine is one of the elements in Group 17 of the Periodic Table.

  1. (a)(i)Describe the colours of the Group 17 elements, chlorine to iodine, at room temperature.[1]
  2. (a)(ii)Describe the relative reactivity of the elements chlorine to iodine as oxidising agents.[1]
  3. (a)(iii)State what is observed when chlorine reacts with hydrogen.[1]
  4. (a)(iv)Explain why the thermal stability of the hydrogen halides decreases down the group.[1]
  5. (b)(i)Define free radical.[1]
  6. (b)(ii)State the essential condition for chlorine to react with C₂H₆ at room temperature.[1]
  7. (b)(iii)Write two equations to show the propagation steps in this reaction. 1 2[2]
  8. (c)(i)Identify a reagent and conditions that can be used to convert chlorine to NaClO.[1]
  9. (c)(ii)Define disproportionation.[1]
  10. (c)(iii)Write numbers in the boxes to balance the equation showing the reaction of propanone with NaClO. CH₃COCH₃ + ☐ NaClO → CHCl₃ + CH₃COONa + ☐ NaOH[1]
  11. (c)(iv)Aqueous AgNO₃ dissolved in ethanol reacts with an aqueous solution of CHCl₃. State what is observed in this reaction. Explain your answer.[2]

Mark scheme

Marking points from the official mark scheme (Oct/Nov 2024). The mark or mark type is shown in brackets.

  1. [1] chlorine = yellow-green; bromine = orange / brown / red; iodine = silver grey / black
  2. [1] oxidising strength decreases from chlorine to iodine
  3. [1] green colour disappears
  4. [1] H–Hal covalent bond strength decreases down the group
  5. [1] a species with one or more unpaired electrons
  6. [1] ultraviolet
  7. [1] C₂H₆ + Cl• → C₂H₅• + HCl
  8. [1] C₂H₅• + Cl₂ → C₂H₅Cl + Cl•
  9. [1] cold NaOH(aq)
  10. [1] a reaction where a species / same species is both oxidised and reduced simultaneously / in the same reaction
  11. [1] CH₃COCH₃ + 3NaCIO → 1CHCl₃ + 1CH₃COONa + 2NaOH
  12. [1] M1 white precipitate/white ppt forms
  13. [1] M2 CHCl₃ is hydrolysed / chloride ions are released OR Cl⁻ / chloride ions which are released react with Ag⁺ OR silver chloride / AgCl is formed

Write your answer and get it marked

On Oracle Prep you can write or photograph your own answer and have it marked by AI against this mark scheme, with feedback on what you missed.

Sign up free →

About this question

Topic
Group 17, A-Level Chemistry (syllabus 9701). Structured question, 13 marks.
Source
A-Level Chemistry, Oct/Nov 2024 Paper 2 Variant 1, question 2.

Questions and mark schemes are from past examination papers and remain the copyright of the exam board. How Oracle Prep builds its content

Related Chemistry questions

© 2026 Oracle Prep