Answer all the questions in the spaces provided.
- (a)(i)State how the solubilities of the hydroxides of the Group 2 elements vary down the group.[1]
- (a)(ii)Explain the factors that are responsible for this variation.[3]
- (b)(i)The solubility of Sr(OH)2 is 3.37 × 10-2 mol dm⁻³ at 0°C. Write an expression for the solubility product of Sr(OH)2. Ksp =[1]
- (b)(ii)Calculate the value of Ksp at 0°C. Include units in your answer. Ksp = units =[2]
- (c)(i)Metal peroxides contain the ¯O–O– ion. The peroxides of the Group 2 elements, MO₂, decompose on heating to produce a single gas and the solid oxide, MO, only. Write an equation for the thermal decomposition of strontium peroxide, SrO2.[1]
- (c)(ii)Suggest how the temperature at which thermal decomposition of MO2 occurs varies down Group 2. Explain your answer.[3]
- (d)(i)The ethanedioates of the Group 2 elements, MC2O4, decompose on heating to produce a mixture of two different gases and the solid oxide, MO, only. Complete the equation for the thermal decomposition of barium ethanedioate. BaC2O4 →[1]
- (d)(ii)Describe two observations you would make during the reaction when ethanedioic acid, H2C2O4, is warmed with acidified manganate(VII) ions.[2]
Mark scheme
Marking points from the official mark scheme (Feb/Mar 2018). The mark or mark type is shown in brackets.
- [1] (solubility) increases (down the group)
- [3] down the group: lattice energy or hydration energy decrease lattice energy decreases more than hydration energy enthalpy change of solution becomes more negative / exothermic
- [1] Ksp = [Sr²+][OH-]²
- [2] Ksp = (3.37 × 10¯²) × (6.74 × 10~²)² = 1.5 × 10¯⁶ units: mol³ dm¯⁹
- [1] 2 SrO2→ 2SrO + O2
- [3] temperature will increase (down the group) charge density of cation decreases (down the group) this means less polarisation of the O22 ion or weakens the O-O bond less
- [1] BaC2O4→) BaO + CO + CO2
- [2] the KMnO4 would decolourise bubbles / gas evolution would be seen
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