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A-LevelChemistryGroup 29701/42 · Feb/Mar 2018 · Q114 Marks

Answer all the questions in the spaces provided.

  1. (a)(i)State how the solubilities of the hydroxides of the Group 2 elements vary down the group.[1]
  2. (a)(ii)Explain the factors that are responsible for this variation.[3]
  3. (b)(i)The solubility of Sr(OH)2 is 3.37 × 10-2 mol dm⁻³ at 0°C. Write an expression for the solubility product of Sr(OH)2. Ksp =[1]
  4. (b)(ii)Calculate the value of Ksp at 0°C. Include units in your answer. Ksp = units =[2]
  5. (c)(i)Metal peroxides contain the ¯O–O– ion. The peroxides of the Group 2 elements, MO₂, decompose on heating to produce a single gas and the solid oxide, MO, only. Write an equation for the thermal decomposition of strontium peroxide, SrO2.[1]
  6. (c)(ii)Suggest how the temperature at which thermal decomposition of MO2 occurs varies down Group 2. Explain your answer.[3]
  7. (d)(i)The ethanedioates of the Group 2 elements, MC2O4, decompose on heating to produce a mixture of two different gases and the solid oxide, MO, only. Complete the equation for the thermal decomposition of barium ethanedioate. BaC2O4 →[1]
  8. (d)(ii)Describe two observations you would make during the reaction when ethanedioic acid, H2C2O4, is warmed with acidified manganate(VII) ions.[2]

Mark scheme

Marking points from the official mark scheme (Feb/Mar 2018). The mark or mark type is shown in brackets.

  1. [1] (solubility) increases (down the group)
  2. [3] down the group: lattice energy or hydration energy decrease lattice energy decreases more than hydration energy enthalpy change of solution becomes more negative / exothermic
  3. [1] Ksp = [Sr²+][OH-]²
  4. [2] Ksp = (3.37 × 10¯²) × (6.74 × 10~²)² = 1.5 × 10¯⁶ units: mol³ dm¯⁹
  5. [1] 2 SrO2→ 2SrO + O2
  6. [3] temperature will increase (down the group) charge density of cation decreases (down the group) this means less polarisation of the O22 ion or weakens the O-O bond less
  7. [1] BaC2O4→) BaO + CO + CO2
  8. [2] the KMnO4 would decolourise bubbles / gas evolution would be seen

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About this question

Topic
Group 2, A-Level Chemistry (syllabus 9701). Structured question, 14 marks.
Source
A-Level Chemistry, Feb/Mar 2018 Paper 4 Variant 2, question 1.

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