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A-LevelChemistryReaction kinetics9701/21 · May/June 2025 · Q310 Marks

Hexene reacts with hydrogen gas to produce hexane. reaction 1 C6H12(I) + H2(g) → C6H14(I) Fig. 3.1 shows the distribution of energies of H2(g) molecules at temperature T. [Figure 3.1]

  1. (a)(i)Sketch on Fig. 3.1 the shape of the curve for the same sample of H2(g) molecules when the temperature is increased.[2]
  2. (a)(ii)Explain why increasing the temperature increases the rate of reaction 1.[2]
  3. (a)(iii)State the role of nickel when it is added to reaction 1.[1]
  4. (a)(iv)Annotate Fig. 3.2 to show the effect of adding nickel to reaction 1 at temperature T. [Figure 3.2][1]
  5. (b)Define Le Chatelier's principle.[2]
  6. (c)Reaction 2 shows the equilibrium reaction between X(g) and Y(g) to produce Z(g) in a sealed container. reaction 2 aX(g) + bY(g) ⇌ cZ(g) Fig. 3.3 shows the effect of changing pressure on the percentage yield of Z(g) at two different temperatures, 300K and 350K. [Figure 3.3] Deduce two conclusions about reaction 2 using Fig 3.3.[2]

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Mark scheme

Marking points from the official mark scheme (May/June 2025). The mark or mark type is shown in brackets.

  1. [2] Two correct for one mark, all four for two marks: • start at origin • peak sits below the original • peak sits to the right-hand side of the original • new line crosses the original once only AND to the right of the original peak
  2. [2] M1 greater proportion of (H2) molecules have energy greater than or equal to the activation energy/≥ EA; M2 increase in frequency of successful collisions (between H2 and C6H12)
  3. [1] catalyst
  4. [1] annotation to show new EA (nickel / catalyst) further to the left than original EA
  5. [2] M1 (if a change is made at a system is dynamic equilibrium) the equilibrium moves; M2 to minimise the change in conditions
  6. [2] (forward) reaction is exothermic; (a + b) > c

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About this question

Topic
Reaction kinetics, A-Level Chemistry (syllabus 9701). Structured question, 10 marks.
Source
A-Level Chemistry, May/June 2025 Paper 2 Variant 1, question 3.

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