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A-LevelChemistryOrganic synthesisFeb/Mar 2016Paper 1 Q231 Mark

But-2-ene-1,4-diol is converted in two steps through an intermediate X into oxobutanedioic acid. HOCH₂CH=CHCH₂OH but-2-ene-1,4-diol step 1 X step 2 hot, acidified KMnO₄ HO₂CCOCH₂CO₂H oxobutanedioic acid What could be the reagent for step 1 and what is the intermediate X?

Acold, acidified KMnO₄, HOCH₂CH₂CH(OH)CH₂OH
Bhot, acidified K₂Cr₂O₇, HO₂CCH=CHCO₂H
Csteam and concentrated H₂SO₄, HOCH₂CH(OH)CH₂CH₂OH
Dwarm, acidified K₂Cr₂O₇, OHCCH(OH)CH₂CHO

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The correct answer is C. This question tests the candidate's understanding of organic synthesis within the Chemistrysyllabus. The examiner's mark scheme requires...

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Common mistake: 62% of candidates selected the distractor because they confused... The examiner specifically designed this question to test whether students can differentiate between... To secure full marks, candidates must demonstrate...

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About This A-Level Chemistry Question

This multiple-choice question appeared in the Cambridge A-Level Chemistry (9701) Feb/Mar 2016 examination, Paper 1 Variant 2. It tests the topic of Organic synthesis and is worth 1 mark.

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