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Cambridge Past Paper Questions

Browse 23,045questions from 25 years of O-Level & A-Level exams. Click any question to practice.

A-LevelChemistryHalogen derivativesMay/June 2011

1,1-dichloropropane reacts with aqueous sodium hydroxide in a series of steps to give propanal. CH3CH2CHCl2 --NaOH(aq)--> CH3CH2CHO Which term desc...

A-LevelChemistryCarboxylic acids and derivativesMay/June 2011

The ester CH3CH2CH2CO2CH3 is responsible for the aroma of apples. When this ester is hydrolysed by acid in the stomach, what is the empirical formu...

A-LevelChemistryOrganic synthesisMay/June 2011

This question should be answered by considering the reactions of KMnO4 with different functional groups under the stated conditions. The diagram sh...

A-LevelChemistryCarboxylic acids and derivativesMay/June 2011

Which reaction would not give ethanoic acid as a product?

A-LevelChemistryReaction kineticsMay/June 2011

Solid calcium carbonate is added to 100 cm³ of dilute hydrochloric acid and the rate of the reaction is measured. 100 cm³ of distilled water is the...

A-LevelChemistryStates of matterMay/June 2011

Which equations apply to an ideal gas? [p = pressure, V = volume, M = molar mass, ρ = density, c = concentration, R = gas constant, T = temperature...

A-LevelChemistryChemical bondingMay/June 2011

What is involved when a hydrogen bond is formed between two molecules? 1 a hydrogen atom bonded to an atom less electronegative than itself 2 a lon...

A-LevelChemistryNitrogen and sulfurMay/June 2011

When the yellow liquid NCl3 is stirred into aqueous sodium hydroxide, the reaction that occurs can be represented by the following equation. 2NCl3(...

A-LevelChemistryNitrogen and sulfurMay/June 2011

In a car engine pollutant oxide Y, which contains non-metallic element X, is formed. Further oxidation of Y to Z occurs in the atmosphere. In this ...

A-LevelChemistryHydrocarbonsMay/June 2011

Which compounds can be obtained from ethene in a single reaction? 1 CH3CH3 2 CH2CH2 3 HOCH2CH2OH

A-LevelChemistryHydroxy compoundsMay/June 2011

Which compounds when heated under reflux with an excess of hot acidified potassium dichromate(VI), give a product with a chiral centre? 1 CH3CH2CCH...

A-LevelChemistryCarbonyl compoundsMay/June 2011

In the reaction between an aldehyde and HCN, catalysed by NaCN, which statements about the reaction mechanism are correct? 1 A new carbon-carbon bo...

A-LevelChemistryCarboxylic acids and derivativesMay/June 2011

An organic compound, X, will react with an excess of calcium metal to produce a salt with the empirical formula CaC4H6O4. What could be the identit...

A-LevelChemistryReaction kineticsMay/June 2012

The molecular energy distribution curve represents the variation in energy of the molecules of a gas at room temperature. [Figure 1.1] Which curve ...

A-LevelChemistryAtomic structureMay/June 2012

In which species are the numbers of protons, neutrons and electrons all different?

A-LevelChemistryChemical bondingMay/June 2012

What is the most likely shape of a molecule of hydrazine, N2H4?

A-LevelChemistryChemical bondingMay/June 2012

In which species does the underlined atom have an incomplete outer shell?

A-LevelChemistryChemical bondingMay/June 2012

Which solid contains more than one kind of bonding?

A-LevelChemistryStates of matterMay/June 2012

Use of the Data Booklet is relevant to this question. The gas laws can be summarised in the ideal gas equation. pV = nRT 0.96 g of oxygen gas is co...

A-LevelChemistryEquilibriaMay/June 2012

Two moles of compound P were placed in a vessel. The vessel was heated and compound P was partly decomposed to produce Q and R. A dynamic equilibri...

A-LevelChemistryChemical energeticsMay/June 2012

The value of the third ionisation energy of aluminium is 2740 kJ mol⁻¹. Which correctly represents this statement?

A-LevelChemistryEquilibriaMay/June 2012

Methanol is manufactured by reacting carbon dioxide and hydrogen. CO2(g) + 3H2(g) ⇌ CH3OH(g) + H2O(g) ∆H = −49 kJ mol⁻¹ What would increase the equ...

A-LevelChemistryChemical bondingMay/June 2012

Which molecule has the largest overall dipole?

A-LevelChemistryNitrogen and sulfurMay/June 2012

In which substance does nitrogen exhibit the highest oxidation state?

A-LevelChemistryChemical energeticsMay/June 2012

Red lead oxide, Pb3O4, is used in metal priming paints. It can be made by heating PbO in air. 6PbO(s) + O2(g) → 2Pb3O4(s) Which two values are need...

A-LevelChemistryNitrogen and sulfurMay/June 2012

Which gas is present in the exhaust fumes of a car engine in a much greater amount than any other gas?

A-LevelChemistryChemical energeticsMay/June 2012

Slaked lime, Ca(OH)2, may be made from limestone, CaCO3. On heating in a lime kiln at 1000°C, limestone decomposes as follows. reaction 1 CaCO3(s) ...

A-LevelChemistryChemical periodicityMay/June 2012

The period 4 elements gallium (Ga), germanium (Ge), arsenic (As) and selenium (Se) are the elements below aluminium, silicon, phosphorus and sulfur...

A-LevelChemistryGroup 17May/June 2012

Chlorine shows oxidation states ranging from −1 to +7 in its compounds. What are the reagent(s) and conditions necessary for the oxidation of eleme...

A-LevelChemistryGroup 2May/June 2012

What can be seen when a piece of magnesium ribbon is placed in cold water?

A-LevelChemistryChemical periodicityMay/June 2012

Use of the Data Booklet is relevant to this question. Sodium and sulfur react together to form sodium sulfide, Na2S. How do the atomic radius and i...

A-LevelChemistryAtoms, molecules and stoichiometryMay/June 2012

Which substance does not produce a poisonous gas, when burnt in a limited amount of air?

A-LevelChemistryCarboxylic acids and derivativesMay/June 2012

Use of the Data Booklet is relevant to this question. A sample of propyl ethanoate is hydrolysed by heating under reflux with aqueous sodium hydrox...

A-LevelChemistryIntroduction to organic chemistryMay/June 2012

Which diagram gives the skeletal formula of 2-chloropentan-3-ol?

A-LevelChemistryOrganic synthesisMay/June 2012

When 1-bromopropane is treated in succession with two reagents, X and Y, it produces propanoic acid. What are reagents X and Y?

A-LevelChemistryHydrocarbonsMay/June 2012

Isomers X and Y both react with HBr. [Figure 23.1] A mixture of X and Y is reacted with HBr. Which three structures represent three different possi...

A-LevelChemistryHydrocarbonsMay/June 2012

Oct-1-ene, CH3(CH2)5CH=CH2, is subjected to thermal cracking. Which combination of compounds W, X, Y and Z can be obtained? CH2=CH2 W CH3CH=CH2 X C...

A-LevelChemistryHalogen derivativesMay/June 2012

When phenacyl chloride, C6H5COCH2Cl, is reacted with aqueous NaOH, the substitution reaction follows an SN2 mechanism. Which structure represents a...

A-LevelChemistryOrganic synthesisMay/June 2012

Complete combustion of compound X gives carbon dioxide and water only. A sample of X is mixed with aqueous potassium(V) dichromate and boiled under...

A-LevelChemistryCarboxylic acids and derivativesMay/June 2012

A compound Y has the following properties. • It is a liquid at room temperature and atmospheric pressure. • It does not mix completely with water. ...

A-LevelChemistryOrganic synthesisMay/June 2012

Coniine is the major constituent of the poison 'oil of hemlock'. [Figure 28.1] Coniine can be synthesised by reacting ammonia with a dibromo compou...

A-LevelChemistryOrganic synthesisMay/June 2012

A common industrial solvent is a mixture of propanone, CH3COCH3, and pentyl ethanoate CH3CO2(CH2)4CH3. Which reagent would have no reaction with th...

A-LevelChemistryHydroxy compoundsMay/June 2012

An organic compound will decolorise dilute acidified aqueous potassium manganate(VII) on warming, but will not decolorise bromine water. What could...

A-LevelChemistryChemical bondingMay/June 2012

Which of the following molecules and ions have a regular trigonal planar shape?

A-LevelChemistryNitrogen and sulfurMay/June 2012

Ammonia and chlorine react in the gas phase. 8NH3 + 3Cl2 → N2 + 6NH4Cl Which statements are correct?

A-LevelChemistryEquilibriaMay/June 2012

Concentrated sulfuric acid behaves as a strong acid when it reacts with water. H2SO4(l) + aq → H+(aq) + HSO4⁻(aq) The HSO4⁻ ion formed behaves as a...

A-LevelChemistryAnalytical techniquesMay/June 2012

Silver chloride dissolves in aqueous ammonia. What happens in this process?

A-LevelChemistryChemical bondingMay/June 2012

Compared with the HCl molecule, the bond .....X..... of the HBr molecule is .....Y...... Which pairs of words correctly complete the above sentence?

A-LevelChemistryEquilibriaMay/June 2012

Which statements are true about the Haber process for the manufacture of ammonia?

A-LevelChemistryHydrocarbonsMay/June 2012

Which compounds can be obtained from propene in a single reaction?

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