Fig. 3.1 shows gas at room temperature. The gas is trapped in a metal cylinder by a metal piston fixed in position. [Figure 3.1]
- (a)Explain, in terms of electrons and the atoms of the metal, how thermal energy is transferred through the walls of the metal cylinder.[3]
- (b)The piston is fixed in position so the pressure of the gas increases as the temperature of the gas increases.
- (b)(i)State what happens to the motion of the particles of the gas as the temperature increases.[1]
- (b)(ii)Explain, in terms of the particles of the gas, why the pressure the gas exerts on the walls of the metal cylinder increases as the temperature increases.[3]
- (c)The gas in the cylinder reaches a temperature of 100 °C. The piston is released and moves to the right. The temperature remains at 100°C. The pressure of the gas now decreases.
- (c)(i)Explain, in terms of the particles of the gas, why the pressure of the gas now decreases.[1]
- (c)(ii)Eventually, the piston stops moving. Explain why.[2]
This question uses a diagram from the original paper, which isn't shown here. Open the full paper from the past papers archive to see it.
Mark scheme
Marking points from the official mark scheme (Oct/Nov 2024). The mark or mark type is shown in brackets.
- [B1] vibrating atoms / particles (ignore electrons) collide with electrons
- [B1] electrons move (a long distance) through metal
- [B1] (moving) electrons collide / interact with distant atoms (ignore electrons) or electrons carry energy (through metal)
- [B1] their / the particles' (average) speed increases
- [B1] the particles collide (with each other / the walls of the container)
- [B1] they / the particles exert greater impulse / force
- [B1] collide more often / harder with the walls (of the cylinder)
- [B1] (particles are further apart) so fewer collisions in unit time / less frequent collisions / longer time between collisions
- [B1] pressure becomes equal to atmospheric pressure
- [B1] no resultant force on piston or force to the left equals force to the right or air resistance / friction (between piston and cylinder walls) mentioned
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