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A-LevelPhysicsThermodynamics9702/41 · Oct/Nov 2021 · Q313 Marks

Define specific heat capacity.

  1. (a)Define specific heat capacity.[2]
  2. (b)(i)A sealed container of fixed volume V contains N molecules, each of mass m, of an ideal gas at pressure p. State an expression, in terms of V, N, p and the Boltzmann constant k, for the thermodynamic temperature T of the gas.[1]
  3. (b)(ii)Show that the mean translational kinetic energy E_K of a molecule of the gas is given by E_K = (3/2)kT.[2]
  4. (b)(iii)Explain why the internal energy of the gas is equal to the total kinetic energy of the molecules.[2]
  5. (c)(i)The gas in (b) is supplied with thermal energy Q. Explain, with reference to the first law of thermodynamics, why the increase in internal energy of the gas is Q.[2]
  6. (c)(ii)Use the expression in (b)(ii) and the information in (c)(i) to show that the specific heat capacity c of the gas is given by c = 3k / 2m.[2]
  7. (d)The container in (b) is now replaced with one that does not have a fixed volume. Instead, the gas is able to expand, so that the pressure of the gas remains constant as thermal energy is supplied. Suggest, with a reason, how the specific heat capacity of the gas would now compare with the value in (c)(ii).[2]

Mark scheme

Marking points from the official mark scheme (Oct/Nov 2021). The mark or mark type is shown in brackets.

  1. [B1] (thermal) energy per unit mass (to cause temperature change)
  2. [B1] (thermal) energy per unit change in temperature
  3. [B1] (T =) pV / Nk
  4. [M1] (pV =) NkT = ⅓Nm<c²> or pV = NkT and_ pV = ⅓Nm<c²>
  5. [A1] leading to ½m<c²> = (3/2)kT and ½m<c²> = E_K
  6. [B1] internal energy = ΣE_K (of molecules) + ΣE_P (of molecules) or no forces between molecules
  7. [B1] potential energy of molecules is zero
  8. [B1] increase in internal energy = Q + work done
  9. [B1] constant volume so no work done
  10. [C1] c = Q/NmΔT
  11. [A1] = [N × (3/2)kΔT] / (NmΔT) = 3k/2m
  12. [B1] (as it expands) gas does work (against the atmosphere/external pressure)
  13. [B1] for same temperature rise) more (thermal) energy needed, so larger specific heat capacity

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About this question

Topic
Thermodynamics, A-Level Physics (syllabus 9702). Structured question, 13 marks.
Source
A-Level Physics, Oct/Nov 2021 Paper 4 Variant 1, question 3.

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