Use band theory to explain why, unlike a copper wire, the resistance of an intrinsic semiconductor decreases with an increase of temperature.
Mark scheme
Marking points from the official mark scheme (Feb/Mar 2017). The mark or mark type is shown in brackets.
- [B5] any five from:
- electrons need energy to enter conduction band (from valence band)
- (positively-charged) holes are left in valence band
- moving charge carriers/holes/electrons are current
- (increase of temperature leads to) more (positive and negative) charge carriers/more holes/more electrons so more current
- more charge carriers/holes/electrons gives rise to less resistance
- (increase of temperature causes) greater (amplitude of) vibrations of atoms/ions/lattice
- effect of more charge carriers/holes/electrons is greater than effect of greater vibrations (and so resistance decreases)
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