Phosphorus-32 ( ⁵P) is an isotope of phosphorus that undergoes radioactive decay.
- (a)The most common isotope of phosphorus is phosphorus-31.
- (a)(i)Describe the structure and composition of a neutral atom of phosphorus-31.[2]
- (a)(ii)State how an atom of phosphorus-32 differs from an atom of phosphorus-31.[1]
- (b)Phosphorus-32 decays by beta-particle emission to a stable isotope of sulfur. The half-life for this decay is 2.0 weeks.
- (b)(i)State how a nucleus of this isotope of sulfur is different to a nucleus of phosphorus-32.[1]
- (b)(ii)At time t=0, a radioactive sample contains 3.2 × 10¹¹ atoms of phosphorus-32. At the same moment, the sample contains no atoms of sulfur. This is shown by the cross on Fig. 6.1. On Fig. 6.1, plot a graph to show how the total number of sulfur atoms in the sample changes with t and draw a suitable curve. [Figure 6.1][3]
- (c)State two precautions taken when storing or moving radioactive materials. 1. 2.[2]
This question uses a diagram from the original paper, which isn't shown here. Open the full paper from the past papers archive to see it.
Mark scheme
Marking points from the official mark scheme (Oct/Nov 2020). The mark or mark type is shown in brackets.
- [1] (a)(i) 16 protons (in nucleus) and 16 electrons in shells or 16 protons (in nucleus) 16 electrons around / outside / surrounding / orbiting nucleus
- [1] (a)(i) 15 neutrons (in nucleus)
- [1] (a)(ii) one more neutron (and same number of protons in nucleus) or 15 neutrons in P-31 and 16 in P-32
- [1] (b)(i) one more proton and one neutron fewer c.a.o.
- [1] (b)(ii) point at/line through (2.0, 1.6 × 10¹¹)
- [1] (b)(ii) point at (8.0, 3.0 × 10¹¹) or any other obvious correct point
- [1] (b)(ii) curve of positive and decreasing gradient and through their plotted points to at least 6.0 weeks
- [2] (c) any two from: lead shielding (e.g. lead apron / gloves / container / (lead) glass screen / (lead glass) goggles / (lead glass) glasses large distance (e.g. tongs/forceps / tweezers / manipulator/ carry at centre of large box) minimum time of exposure or wear film badge
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