Oxygen, sulfur, selenium, tellurium and polonium are in Group VI.
- (a)State the percentage composition by volume of oxygen in dry air.[1]
- (b)State one large-scale use for oxygen.[1]
- (c)(i)Explain why both isotopes have the same chemical properties.[1]
- (c)(ii)Give one difference in the atomic structure of these two isotopes.[1]
- (d)Selenium forms a compound that contains only selenium, oxygen and chlorine. The compound contains 9.6% oxygen by mass and 42.8% chlorine by mass. Calculate the empirical formula of this compound. empirical formula[3]
- (e)(i)The temperature of the sample is decreased. The pressure remains constant. Describe and explain, using kinetic particle theory, what happens to the volume of the sample.[1]
- (e)(ii)The pressure of the sample is decreased. The temperature remains constant. Describe and explain, using kinetic particle theory, what happens to the volume of the sample.[1]
- (e)(iii)Calculate the mass of oxygen in the 11.5dm³ sample at room temperature and pressure. Give your answer to two significant figures. mass ... g[2]
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Mark scheme
Marking points from the official mark scheme (May/June 2021). The mark or mark type is shown in brackets.
- [1] 21 (%)
- [1] steel making / welding / cutting metals / oxygen tents in hospitals / breathing apparatus / fuel cells
- [1] same electronic structure / same electronic configuration
- [1] polonium-210 has one more neutron / polonium-209 has one less neutron / polonium-209 has 125 neutrons and polonium-210 has 126 neutrons
- [1] percentage of selenium = 47.6 (1)
- [1] mole ratio Se : O : Cl is 47.6/79 : 9.6/16 : 42.8/35.5 OR 0.60 : 0.60 : 1.21 (1)
- [1] empirical formula SeOCl₂ (1)
- [1] volume decreases
- [0] AND
- [0] particles move slower / particles less spread out / particles closer together
- [1] volume increases
- [0] AND
- [0] particles move further apart / particles more spread out / distance between particles increases
- [1] mol = 11.5/24 OR 0.479(117) (1)
- [1] mass = 15 (g) (1)
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