Carbon dioxide and water vapour are greenhouse gases found in air.
- (a)(i)Name one other greenhouse gas.[1]
- (a)(ii)State one environmental problem that may be caused by an increase in the percentage of carbon dioxide in the air.[1]
- (b)Draw the dot-and-cross diagram to show the bonding in a molecule of carbon dioxide. Only show the outer shell electrons.[1]
- (c)Some power stations burn methane, CH4. Construct the equation to show the complete combustion of methane.[1]
- (d)The carbon dioxide made in power stations can be removed by a reversible reaction with water. CO2(g) + H2O(l) ⇌ H2CO3(aq) The forward reaction is exothermic.
- (d)(i)The concentration of carbon dioxide is increased. The temperature is kept constant. Predict and explain how the position of equilibrium changes.[2]
- (d)(ii)The temperature of the water is increased. All other conditions are kept constant. Predict and explain how the position of equilibrium changes.[2]
- (e)Carbonic acid, H2CO3(aq), is a weak acid.
- (e)(i)What is the meaning of the term weak in weak acid?[1]
- (e)(ii)Carbonic acid contains a small concentration of carbonate ions, CO32-(aq). If carbonic acid is pumped deep underground, the CO32-(aq) will react with metal ions to form insoluble carbonates. Write the ionic equation for the reaction of magnesium ions with CO32-(aq).[1]
This question uses a diagram from the original paper, which isn't shown here. Open the full paper from the past papers archive to see it.
Mark scheme
Marking points from the official mark scheme (May/June 2021). The mark or mark type is shown in brackets.
- 6(a)(i) methane
- 6(a)(ii) global warming
- 6(b) O=C=O with correct outer shell electrons (1)
- 6(c) CH4 + 2O2 → CO2 + 2H2O
- 6(d)(i) position of equilibrium moves to the right (1)
- 6(d)(i) to use up the extra carbon dioxide / to reduce the concentration of carbon dioxide (1)
- 6(d)(ii) position of equilibrium moves to the left (1)
- 6(d)(ii) to absorb heat/because forward reaction is exothermic / backward reaction is endothermic (1)
- 6(e)(i) little dissociation (to form ions)
- 6(e)(ii) Mg2+ + CO32- → MgCO3
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