Iron is a transition element.
- (a)State two physical properties of iron that are typical of a transition element. 1. 2.[2]
- (b)Name an industrial process that uses iron as a catalyst.[1]
- (c)(i)Iron(II) sulfate thermally decomposes to form iron(III) oxide, sulfur dioxide and sulfur trioxide. 2FeSO4(s) -> Fe2O3(s) + SO2(g) + SO3(g) Explain how the equation shows that this reaction involves oxidation.[1]
- (c)(ii)A sample of 6.08 g of FeSO4 is heated until all the sample has thermally decomposed. Calculate the volume of sulfur dioxide formed, SO2(g), in dm³, measured at room temperature and pressure. volume of sulfur dioxide ............................................................ dm³[3]
- (d)Iron(III) oxide reacts with dilute sulfuric acid to make iron(III) sulfate, Fe2(SO4)3. Construct the equation for this reaction.[1]
- (e)Describe a chemical test that can be used to distinguish between aqueous solutions of iron(II) sulfate and iron(III) sulfate. chemical test .......................................................................................... result with iron(II) sulfate ......................................................................... result with iron(III) sulfate .........................................................................[2]
Mark scheme
Marking points from the official mark scheme (May/June 2020). The mark or mark type is shown in brackets.
- [2] Any two from: high boiling point / high melting point (1); high density (1); good electrical conductor / good thermal conductor (1); lustrous (1); sonorous (1)
- [1] Haber (process)
- [1] iron(II) ions lose electrons
- [3] moles of FeSO4 = 6.08/152 OR 0.04 (1) moles of SO2 (= 0.5 × 0.04) = 0.02 (1) volume of SO2 (= 24 × 0.02) = 0.48 (dm³) (1)
- [1] Fe2O3 + 3H2SO4 → Fe2(SO4)3 + 3H2O
- [2] (aqueous) ammonia / (aqueous) sodium hydroxide (1) iron(II) sulfate – green ppt AND iron(III) sulfate – rusty / red-brown / orange / orange-brown ppt (1)
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