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O-LevelChemistryRates of Reaction5070/21 · May/June 2020 · Q38 Marks

The equation for the decomposition of hydrogen peroxide is shown. 2H2O2 -> 2H2O + O2 A sample containing 1.00 mol of hydrogen peroxide is completely decomposed. This sample releases 98.0 kJ of heat energy.

  1. (a)Calculate the heat energy released when 680g of hydrogen peroxide is completely decomposed. heat energy released ................................................................ kJ[2]
  2. (b)Use ideas about bond breaking and bond forming to explain why the decomposition of hydrogen peroxide is exothermic.[2]
  3. (c)The energy profile diagram for the decomposition of hydrogen peroxide is shown. [Diagram shows an energy profile with reactants (2H2O2) at a higher energy level than products (2H2O + O2). The activation energy peak is labelled B, and the overall energy change from reactants to products is labelled A.] Identify the energy changes. change A ............................................................................................ change B ............................................................................................[2]
  4. (d)The rate of decomposition of hot H2O2 is greater than that of cold H2O2. Use ideas about particles to explain why.[2]

This question uses a diagram from the original paper, which isn't shown here. Open the full paper from the past papers archive to see it.

Mark scheme

Marking points from the official mark scheme (May/June 2020). The mark or mark type is shown in brackets.

  1. [2] (moles of H2O2) = 680/34 OR 20 (1) (energy = 20 × 98) = 1960 (kJ) (1)
  2. [2] bond breaking is endothermic and bond making is exothermic / bond breaking absorbs energy and bond making releases energy(1) more energy released (in bond making) than absorbed (in bond breaking) (1)
  3. [2] A is enthalpy change / ∆H (1) B is activation energy / Ea (1)
  4. [2] particles have more energy / particles moving faster (1) more successful collisions / more particles with energy equal or above activation energy (1)

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About this question

Topic
Rates of Reaction, O-Level Chemistry (syllabus 5070). Structured question, 8 marks.
Source
O-Level Chemistry, May/June 2020 Paper 2 Variant 1, question 3.

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