A sample of waste includes plastic and copper.
- (a)One of the plastics is the addition polymer poly(chloroethene). Complete the equation to show the formation of poly(chloroethene). [Figure 9.1][2]
- (b)(i)Plastic waste is disposed of by combustion. (i) Complete the equation to show the complete combustion of poly(chloroethene). The empirical formula of poly(chloroethene), C2H3Cl, is used in the equation. C2H3Cl + ...........................O2 → ...........................CO2 + ...........................H2O + ...........................HCl[1]
- (b)(ii)Suggest why the combustion of poly(chloroethene) will contribute to the formation of acid rain.[1]
- (c)(i)Some waste plastics, such as nylon, are polyamides. (i) Give one large scale use of nylon.[1]
- (c)(ii)The structure shows a monomer that can be used to make a polyamide. [Figure 9.2] Draw the partial structure of this polyamide. Show two repeat units.[1]
- (d)Copper waste is melted and then cooled to make new objects. Use the kinetic particle theory to describe the changes in movement and arrangement of the particles when a liquid cools to become a solid.[2]
- (e)Explain, in terms of structure and bonding, why copper has a high melting point.[2]
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Mark scheme
Marking points from the official mark scheme (May/June 2019). The mark or mark type is shown in brackets.
- [2] 9(a) correct monomer (1) correct use of n in front of monomer to balance the equation (1)
- [1] 9(b)(i) 2C2H3Cl + 5O2 → 4CO2 + 2H2O + 2HCl (1)
- [1] 9(b)(ii) HCl is an acid(ic gas) (1)
- [1] 9(c)(i) clothing / sleeping bags / rope / parachutes / fishing line / curtain materials (1)
- [1] 9(c)(ii) (1)
- [2] 9(d) liquid / it changes from moving to vibrating / particles sliding over each other (in liquid) to vibrating (in solid) (1) liquid / it changes from disordered to ordered (in solid) / (particles) changing from irregularly arranged (in liquid) to regularly arranged (in solid) (1)
- [2] 9(e) positive ions in a sea of electrons (1) strong attraction between electrons and (positive) ions (1)
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