Ammonium carbonate, (NH₄)₂CO₃, is a white solid which decomposes when heated. (NH₄)₂CO₃(s) ⇌ 2NH₃(g) + CO₂(g) + H₂O(g)
- (a)A small sample of ammonium carbonate is heated in a test-tube. Describe how you will know when all the ammonium carbonate has decomposed.[1]
- (b)Calculate the total volume of ammonia and carbon dioxide, measured at room temperature and pressure, formed when 4.80g of ammonium carbonate is completely decomposed.[3]
- (c)Describe a chemical test for the ammonium ion. test observation[2]
- (d)Aqueous ammonium carbonate reacts with dilute hydrochloric acid. Construct the ionic equation, including state symbols, for this reaction.[2]
- (e)Solid ammonium carbonate does not conduct electricity. Aqueous ammonium carbonate conducts electricity. Explain these two observations.[2]
Mark scheme
Marking points from the official mark scheme (May/June 2019). The mark or mark type is shown in brackets.
- [1] solid disappears / ammonium carbonate disappears / nothing left in tube (1)
- [3] moles of ammonium carbonate = 4.80 /96 OR 0.05(00) (1)
- [3] moles of gas = 3 × 0.05 OR 0.15 (1)
- [3] volume of gas = (0.15 × 24) = 3.6 dm³ OR 3600 cm³ (1)
- [2] heat or warm with (aqueous) sodium hydroxide (1)
- [2] gas that turns (moist red) litmus blue (1)
- [2] CO₃²⁻(aq) + 2H⁺(aq) → CO₂(g) + H₂O(l)
- [2] correct formulae (1)
- [2] correct state symbols – dependent on correct formulae (1)
- [2] in solid ions cannot move (1)
- [2] in aqueous solution ions can move (1)
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