Methanesulfonic acid has the structure shown. [Figure showing structure of methanesulfonic acid] H O | || H—C—S—O | || | H O H
- (a)Write the molecular formula for methanesulfonic acid.[1]
- (b)Methanesulfonic acid is a stronger acid than ethanoic acid. Explain the meaning of this statement.[1]
- (c)What is the difference between an aqueous acid and an aqueous alkali, in terms of the ions present?[2]
- (d)What is the mass of methanesulfonic acid needed to make 150 cm³ of a 0.150 mol/dm³ solution? mass ..................................................... g[3]
- (e)In a titration, 0.00150 moles of NaOH is exactly neutralised by 0.175 mol/dm³ methanesulfonic acid. One mole of sodium hydroxide reacts with one mole of methanesulfonic acid. Calculate the volume, in cm³, of aqueous methanesulfonic acid needed in this titration. volume ..................................................... cm³[1]
- (f)(i)Methanesulfonic acid reacts with magnesium to make a salt and a gas. Name the gas made in this reaction.[1]
- (f)(ii)The formula of the anion in the salt is CH3SO3⁻. Write the formula of the salt formed.[1]
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Mark scheme
Marking points from the official mark scheme (May/June 2018). The mark or mark type is shown in brackets.
- [1] 8(a) CH4SO3
- [1] 8(b) methanesulfonic acid is more dissociated
- [2] 8(c) acids contain H⁺ (1) alkalis contain OH⁻ (1)
- [3] 8(d) moles of acid = 0.0225/0.15 × 0.150 (1) Mr of acid = 96 (1) mass of acid (= moles of acid × Mr) = 2.16 (1)
- [1] 8(e) 8.57 (cm³) (1)
- [1] 8(f)(i) hydrogen
- [1] 8(f)(ii) Mg(CH3SO3)2
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