Silicon is a non-metal found in Group IV of the Periodic Table.
- (a)Silicon is manufactured by the reduction of silicon dioxide with carbon. SiO2 + 2C → Si + 2CO What is the maximum mass of silicon that can be made from 300 g of silicon dioxide? mass of silicon ..................................................... g[2]
- (b)Silicon has a giant molecular structure. Suggest two physical properties of silicon. 1 2[2]
- (c)(i)Silane has the molecular formula SiH4. Draw the ‘dot-and-cross' diagram for silane. You only need to show the outer shell electrons of silicon.[1]
- (c)(ii)Using ideas about structure and bonding, suggest why silane has a low boiling point.[2]
- (d)(i)Siloxanes are condensation polymers. The partial structure of a siloxane can be represented as shown. CH3 CH3 CH3 CH3 -O-Si—O—Si —O—Si — O-Si- CH3 CH3 CH3 CH3 What is meant by the term condensation polymerisation?[2]
- (d)(ii)Draw the repeat unit of this siloxane.[1]
- (e)Butene forms an addition polymer called poly(butene). CH3 H₂C C C H H H butene Draw a partial structure for poly(butene). You must show at least two repeat units.[1]
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- [2] 5(a) moles of SiO2 = 5 / percentage of Si in SiO2 = 46.67 (1) mass of Si (= moles of SiO2 × 28) = 140 (1)
- [2] 5(b) Any two from: high melting point / high boiling point (1) poor conductor of electricity (1) does not dissolve (in water) (1) (very) hard (1)
- [1] 5(c)(i) correct 'dot-and-cross' diagram for silane (1)
- [2] 5(c)(ii) has a simple (molecular or covalent) structure (1) weak intermolecular forces / van der Waals' forces between molecules / easy to overcome the forces between molecules / weak forces between molecules / easy to break attraction between molecules (1)
- [2] 5(d)(i) monomers react together / monomers combine / monomers join / monomers link (1) form a polymer and another molecule (1)
- [1] 5(d)(ii) CH3 | -!S-O- CH3 (1)
- [1] 5(e) CH3 CH3 3ייץ 3 CH₂H CH₂H -C—C—C—C ΗΗΗ Η (1)
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