Iodine reacts with chlorine to form iodine(I) chloride, ICl. I₂ + Cl₂ → 2ICl Iodine(I) chloride reacts in a similar way to both iodine and chlorine.
- (a)Sodium reacts with iodine(I) chloride. Construct the equation for the reaction between sodium and iodine(I) chloride.[1]
- (b)Iodine(I) chloride reacts with ethene. Draw the structure of the product of this reaction. Show all of the atoms and all of the bonds.[1]
- (c)Iodine(I) chloride reacts with ethane in the presence of ultraviolet light. Deduce the type of reaction that takes place and construct an equation for this reaction. type of reaction .......................................................................................... equation ....................................................................................................[2]
- (d)Draw a 'dot-and-cross' diagram to show a molecule of iodine(I) chloride. Only show the outer shell electrons.[1]
- (e)(i)Iodine(I) chloride reacts with chlorine to form iodine(III) chloride. This reaction is investigated at 200°C in a sealed container. A dynamic equilibrium mixture is established. ICl(g) + Cl₂(g) ⇌ ICl₃(g) ICl(g) is a dark brown gas. ICl₃(g) is a yellow gas. What is meant by the term dynamic equilibrium? Refer to both rate of reaction and concentration in your answer.[3]
- (e)(ii)The pressure of the equilibrium mixture is increased. The temperature is kept at 200 °C. Predict and explain what will happen to the colour of the equilibrium mixture.[2]
This question uses a diagram from the original paper, which isn't shown here. Open the full paper from the past papers archive to see it.
Mark scheme
Marking points from the official mark scheme (May/June 2017). The mark or mark type is shown in brackets.
- B8(a) 2Na + ICl NaCl + NaI (1)
- B8(b) HH
- H-C-C-H
- Cl I (1)
- B8(c) substitution (1)
- C2H6 + ICl C2H5Cl + HI
- OR
- C2H6 + ICl C2H5I + HCl (1)
- B8(d) Correct 'dot-and-cross' diagram (1)
- XX
- I Cl
- XX
- B8(e)(i) Reversible reaction (1)
- Rate of forward reaction is the same as rate of backward reaction (1)
- So that the concentrations of reactants and products do not change (1)
- B8(e)(ii) The colour becomes less brown / colour becomes more yellow (1)
- Fewer moles on right hand side so position of equilibrium moves to the right / fewer moles on product side so position of equilibrium moves to the right (1)
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