Alkenes are a homologous series of unsaturated hydrocarbons. The table shows information about some alkenes. [Figure B9.1]
- (a)Decene is a liquid at 25°C. How can you make this deduction from the data in the table?[2]
- (b)Butene boils at –6°C. Use the kinetic particle theory to explain what happens when butene boils.[2]
- (c)A sample of ethene gas in a gas syringe is heated from 20°C to 100°C. The pressure remains constant. Describe and explain, in terms of the kinetic particle theory, what happens to the volume of the gas.[2]
- (d)At room temperature ethene diffuses faster than butene. Explain why.[1]
- (e)Draw the structure, showing all the atoms and all the bonds, for two isomers with the molecular formula C4H8.[2]
- (f)The structure of hexene is shown. [Figure B9.2] Draw the structure, showing all the atoms and all the bonds, for the product of the reaction of hexene with steam.[1]
This question uses a diagram from the original paper, which isn't shown here. Open the full paper from the past papers archive to see it.
Mark scheme
Marking points from the official mark scheme (May/June 2015). The mark or mark type is shown in brackets.
- [2] (a) Melting point below 25 °C (1)
- Boiling point above 25°C (1)
- [2] (b) Particles move faster/particles gain energy (1)
- Particles spread out/move away from each other (1)
- [2] (c) Volume of gas increases (1)
- Particles spread out (1)
- [1] (d) Ethene has a lower (relative) molecular mass/ethene has a lower formula mass/or reverse argument (1)
- [2] (e) ANY TWO FROM (1 mark each structure for C4H8 isomers)
- [1] (f) (1 mark for product of hexene + steam)
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