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O-LevelChemistryBonding & Structure5070/21 · May/June 2015 · Q412 Marks

Two isotopes of sulfur are ³²₁₆S and ³³₁₆S.

  1. (a)What is meant by the term isotopes?[1]
  2. (b)Complete the table for ³³₁₆S. number of neutrons number of protons electronic configuration[3]
  3. (c)Sulfur forms simple molecules which have a relative molecular mass of 256. Suggest the formula of a sulfur molecule.[1]
  4. (d)(i)Sulfur has a low melting point and does not conduct electricity. Explain why sulfur has a low melting point.[1]
  5. (d)(ii)Explain why sulfur does not conduct electricity.[1]
  6. (e)Sulfur reacts with potassium to form potassium sulfide. Write the formula and the electronic configuration of the positive ion and of the negative ion in potassium sulfide. positive ion formula ..................................................... electronic configuration .................................................. negative ion formula ..................................................... electronic configuration ..................................................[2]
  7. (f)Sulfur reacts with hydrogen to form hydrogen sulfide, H2S. Draw the 'dot-and-cross' diagram to show the bonding in a molecule of hydrogen sulfide. Only draw the outer shell electrons.[2]
  8. (g)Hydrogen sulfide reacts with sulfur dioxide to form sulfur and water. Write the equation for this reaction.[1]

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Mark scheme

Marking points from the official mark scheme (May/June 2015). The mark or mark type is shown in brackets.

  1. [1] (a) Atoms with same number of protons and different number of neutrons/atoms with same atomic number and different mass number (1)
  2. [1] (b) number of neutrons 17 (1) number of protons 16 (1) electronic configuration 2.8.6 (1)
  3. [1] (c) S8 (1)
  4. [1] (d) (i) Weak intermolecular forces/weak attraction between molecules (1)
  5. [1] (d) (ii) No free electrons/no delocalised electrons/all electrons used in bonding/no mobile electrons (1)
  6. [1] (e) K⁺ and 2.8.8 (1) S²⁻ and 2.8.8 (1)
  7. [1] (f) Both shared pairs between H and S (1) Rest of structure correct (1)
  8. [1] (g) 2H2S + SO2 → 3S + 2H2O (1)

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About this question

Topic
Bonding & Structure, O-Level Chemistry (syllabus 5070). Structured question, 12 marks.
Source
O-Level Chemistry, May/June 2015 Paper 2 Variant 1, question 4.

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