Concentrated aqueous magnesium iodide is electrolysed using graphite electrodes. Predict the product at each electrode. anode cathode
- (a)Concentrated aqueous magnesium iodide is electrolysed using graphite electrodes. Predict the product at each electrode. anode cathode[2]
- (b)Molten magnesium iodide is electrolysed using graphite electrodes. Construct the ionic half-equation for the reaction at each electrode when molten magnesium iodide is electrolysed. anode cathode[2]
- (c)Describe a test for aqueous iodide ions. Include the observations for a positive result. test observations[2]
- (d)Iodide ions reduce manganese(IV) oxide, MnO₂, to Mn²⁺ ions. 2I⁻ + MnO₂ + 4H⁺ → Mn²⁺ + I₂ + 2H₂O
- (d)(i)Explain, in terms of movement of electrons, how iodide ions act as a reducing agent in this reaction.[1]
- (d)(ii)State the name of the type of reaction that involves simultaneous oxidation and reduction.[1]
- (e)Phosphorus(III) iodide is produced when phosphorus reacts with iodine. Complete Fig. 4.1 to show the dot-and-cross diagram for a molecule of phosphorus(III) iodide. Show only the outer shell electrons. [Figure 4.1][2]
This question uses a diagram from the original paper, which isn't shown here. Open the full paper from the past papers archive to see it.
Mark scheme
Marking points from the official mark scheme (Oct/Nov 2023). The mark or mark type is shown in brackets.
- [1] anode: iodine (1)
- [1] cathode: hydrogen (1)
- [1] anode: 2I⁻ → I₂ + 2e⁻ (1)
- [1] cathode: Mg²⁺ + 2e⁻ → Mg (1)
- [1] add (acidified) silver nitrate (1)
- [1] (light) yellow precipitate (1)
- [1] iodide (ions) give electrons to the Mn in MnO2
- [1] redox
- [1] pair of electrons between each P and I (1)
- [1] 6 non-bonding electrons on each I AND 2 non-bonded electrons on P (1)
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