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O-LevelChemistryOrganic Chemistry5070/22 · Oct/Nov 2022 · Q710 Marks

This question is about carboxylic acids and polymers.

  1. (a)The structure of an organic compound is shown. [Figure 7.1 - Dicarboxylic acid structure] Deduce the molecular formula of this compound.[1]
  2. (b)Propanoic acid, C2H5COOH, reacts with methanol, CH3OH, to form an ester.
  3. (b)(i)Name this ester. Draw the structure of this ester showing all atoms and all bonds. name of ester structure of ester[2]
  4. (b)(ii)State one use of esters.[1]
  5. (c)Ethanoic acid can be produced by the bacterial oxidation of ethanol. Give one other method of oxidising ethanol to produce ethanoic acid.[2]
  6. (d)The simplified structures of a dicarboxylic acid monomer and a diamine monomer are shown. [Figure 7.2 - Monomer structures]
  7. (d)(i)Draw the partial structure of the condensation polymer formed from these two monomers to show: • two repeat units • all of the atoms and all of the bonds in the amide linkages.[2]
  8. (d)(ii)State the meaning of the term condensation in condensation polymerisation.[1]
  9. (e)Proteins have amide linkages. Proteins are hydrolysed using dilute acid. Name the type of compound produced by this hydrolysis.[1]

This question uses a diagram from the original paper, which isn't shown here. Open the full paper from the past papers archive to see it.

Mark scheme

Marking points from the official mark scheme (Oct/Nov 2022). The mark or mark type is shown in brackets.

  1. [1] 7(a) C4H6O5
  2. [2] 7(b)(i) methyl propanoate (1); [structure of methyl propanoate showing all atoms and bonds] (1)
  3. [1] 7(b)(ii) solvents / perfumes / flavourings
  4. [2] 7(c) potassium manganate(VII) / KMnO4 (1); acid / acidified (1)
  5. [2] 7(d)(i) two repeat units with continuation bonds (1); at least two amide linkages -N-C(=O)- (1)
  6. [1] 7(d)(ii) joining of two compounds with elimination of a small molecule / joining of two compounds removal of small molecule
  7. [1] 7(e) amino acids

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About this question

Topic
Organic Chemistry, O-Level Chemistry (syllabus 5070). Structured question, 10 marks.
Source
O-Level Chemistry, Oct/Nov 2022 Paper 2 Variant 2, question 7.

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