This question is about alcohols and polymers.
- (a)The structure of an organic compound is shown. H-O ΗΗΗ C-C-C-C-O-H O ΗΗΗ Deduce the molecular formula of this compound.[1]
- (b)(i)An isomer of butanol has the structure shown. ΗΗΗΗ H-C-C-C-C-O-H ΗΗΗΗ State the meaning of the term isomerism.[1]
- (b)(ii)Draw the structure of a different isomer of butanol.[1]
- (b)(iii)Butanol reacts with ethanoic acid, CH3COOH, to form an ester. Name this ester. Draw the structure of this ester. Show all of the atoms and all of the bonds. name of ester structure of ester[2]
- (c)The partial structure of a polyester is shown. --O-C(=O)-(CH2)6-C(=O)-O-(CH2)6-O-- Draw the structures of the two monomers used to make this polyester.[2]
- (d)(i)Terylene is a polyester. State one use of Terylene.[1]
- (d)(ii)Name a naturally occurring molecule which has the same ester linkage as Terylene.[1]
- (e)Starch is a polymer which can be hydrolysed. State the meaning of the term hydrolysis.[1]
This question uses a diagram from the original paper, which isn't shown here. Open the full paper from the past papers archive to see it.
Mark scheme
Marking points from the official mark scheme (Oct/Nov 2022). The mark or mark type is shown in brackets.
- [1] C4H8O3
- [1] compounds with the same molecular formula but with different structures / compounds with the same molecular formula but with different arrangement of atoms (1)
- [1] structure of any isomer of butan-1-ol correctly drawn
- [2] butyl ethanoate (1)
- [2] [Diagram of butyl ethanoate structure] (1)
- [2] HO(CH2)6OH (1)
- [2] HOOC(CH2)6COOH (1)
- [1] clothing
- [1] fat
- [1] breakdown of a substance by water
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