The alkenes are a homologous series of hydrocarbons.
- (a)Give the general formula for the alkenes.[1]
- (b)(i)The structure of an alkene is shown. ΗΗΗΗ H-C-C-C=C-H HH Name this alkene.[1]
- (b)(ii)Explain how this structure shows that alkenes are: unsaturated hydrocarbons.[2]
- (c)Alkenes are produced by cracking some fractions obtained from the fractional distillation of petroleum (crude oil). State the meaning of the term cracking.[2]
- (d)Carbon monoxide is formed when alkenes undergo incomplete combustion. State one effect of carbon monoxide on health.[1]
- (e)(i)Alkenes react with bromine to form compounds containing carbon, hydrogen and bromine. A compound contains 22.2% carbon, 3.70% hydrogen and 74.1% bromine by mass. Calculate the empirical formula of this compound. empirical formula[2]
- (e)(ii)A different compound of carbon, hydrogen and bromine has the empirical formula C3H2Br. The relative molecular mass of this compound is 236. Deduce the molecular formula of this compound. molecular formula[1]
This question uses a diagram from the original paper, which isn't shown here. Open the full paper from the past papers archive to see it.
Mark scheme
Marking points from the official mark scheme (Oct/Nov 2022). The mark or mark type is shown in brackets.
- [1] CnH2n
- [1] butene
- [2] unsaturated: has C=C bond / has carbon-carbon double bond (1)
- [2] hydrocarbon: contains only hydrogen and carbon / contains hydrogen and carbon and no other element (1)
- [2] breakdown / decomposition (1)
- [2] idea of long chain hydrocarbons to short chain hydrocarbons / larger hydrocarbons to smaller hydrocarbons (1)
- [1] poisonous / toxic
- [2] division by correct relative atomic mass e.g. C = 22.2/12, H = 3.7/1, Br = 74.1/80 OR 1.85, 3.7, 0.93 (1)
- [2] division by lowest value to get correct answer 1.85/0.93, 3.7/0.93, 0.93/0.93 C2H4Br (1)
- [1] C6H4Br2
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