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O-LevelChemistryRates of Reaction5070/21 · Oct/Nov 2021 · Q311 Marks

Iron powder reacts with dilute sulfuric acid. Fe(s) + H₂SO₄(aq) → FeSO₄(aq) + H₂(g) (a) The graph shows the volume of hydrogen gas produced at 20°C as the reaction proceeds. [Figure 3.1]

  1. (a)(i)State how long it takes from the start of the experiment to collect 18cm³ of hydrogen gas.[1]
  2. (a)(ii)The experiment is repeated at 30°C. All other conditions are the same. Draw a line on the grid to show how the volume of hydrogen gas produced changes with time when the reaction is done at 30°C.[2]
  3. (b)(i)Describe and explain, using ideas about collisions between particles, how the rate of the reaction changes when the temperature of the reaction mixture is increased. All other conditions are the same.[2]
  4. (b)(ii)Describe and explain, using ideas about collisions between particles, how the rate of the reaction changes when larger pieces of iron are used. All other conditions are the same.[2]
  5. (c)Calculate the maximum volume, in dm³, of hydrogen formed when 3.36g of iron react with excess dilute sulfuric acid at room temperature and pressure. Give your answer to three significant figures. maximum volume =[2]
  6. (d)Concentrated sulfuric acid is an oxidising agent. Describe a test for oxidising agents. test observations[2]

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Mark scheme

Marking points from the official mark scheme (Oct/Nov 2021). The mark or mark type is shown in brackets.

  1. [1] 3(a)(i) 6 minutes
  2. [1] 3(a)(ii) initial gradient steeper and starting from origin
  3. [1] 3(a)(ii) line levels off at 34 cm³ gas
  4. [2] 3(b)(i) rate of reaction increases (no mark); particles move faster / particles have more kinetic energy (1); more particles have activation energy (or above)/ more successful collisions / more energetic collisions (1)
  5. [2] 3(b)(ii) rate of reaction decreases (no mark); fewer particles exposed on surface / fewer particles (of iron) per unit area / fewer particles per cm² (1); collision frequency decreases / fewer particles collide per second / collision rate decreases / collisions less often (1)
  6. [1] 3(c) mol iron = 3.36 / 56 OR 0.060 mol
  7. [1] 3(c) volume of hydrogen = 1.44 (dm³)
  8. [1] 3(d) add (aqueous) potassium iodide
  9. [1] 3(d) colourless to brown solution

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About this question

Topic
Rates of Reaction, O-Level Chemistry (syllabus 5070). Structured question, 11 marks.
Source
O-Level Chemistry, Oct/Nov 2021 Paper 2 Variant 1, question 3.

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