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O-LevelChemistryRates of Reaction5070/22 · Oct/Nov 2020 · Q610 Marks

Methanoic acid and ethanoic acid are weak acids.

  1. (a)What does the term weak mean, when applied to acids?[1]
  2. (b)(i)Methanoic acid, HCO2H, reacts with magnesium powder. Construct the equation for this reaction.[1]
  3. (b)(ii)State and explain how the rate of this reaction changes when the experiment is repeated using a piece of magnesium ribbon with the same mass as the powder. All other conditions stay the same. Include in your answer ideas about collisions between particles.[2]
  4. (c)Methanoic acid reacts with propanol, C3H7OH, to form an ester. Name and draw the structure of this ester, showing all of the atoms and all of the bonds. name structure[2]
  5. (d)(i)Ethanoic acid is present in vinegar. Name the organic compound which is converted to ethanoic acid when vinegar is made.[1]
  6. (d)(ii)What type of chemical reaction is this?[1]
  7. (e)(i)The table shows some properties of four carboxylic acids. carboxylic acid | formula | density in g/cm³ | boiling point in °C methanoic acid | HCO₂H | 1.22 | 101 ethanoic acid | CH3CO2H | | 118 propanoic acid | C2H5CO2H | 0.99 | 141 butanoic acid | C3H7CO2H | 0.96 | 164 Predict the density of ethanoic acid. .................................................... g/cm³[1]
  8. (e)(ii)Describe and explain the change in the boiling point as the number of carbon atoms in a molecule increases.[1]

Mark scheme

Marking points from the official mark scheme (Oct/Nov 2020). The mark or mark type is shown in brackets.

  1. [1] 6(a) (acid which is) partially / slightly ionised (in water) / (acid which is) partially / slightly dissociated (in water)
  2. [1] 6(b)(i) 2HCO2H + Mg → (HCO2)2Mg + H2
  3. [1] 6(b)(ii) rate decreases because:
  4. [1] 6(b)(ii) fewer (magnesium) particles exposed / fewer particles on the surface (of the magnesium) (1)
  5. [1] 6(b)(ii) less frequent collisions / particles collide less often / collision rate decreases (1)
  6. [1] 6(c) propyl methanoate (1)
  7. [1] 6(c) O | H H H | | | H-C-O-C-C-C-H | | | H H H (1)
  8. [1] 6(d)(i) ethanol
  9. [1] 6(d)(ii) oxidation
  10. [1] 6(e)(i) values between 1.00 and 1.21 (inclusive)
  11. [1] 6(e)(ii) (boiling points) increase because forces of attraction between molecules are larger / (boiling points) increase because the intermolecular forces increase

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About this question

Topic
Rates of Reaction, O-Level Chemistry (syllabus 5070). Structured question, 10 marks.
Source
O-Level Chemistry, Oct/Nov 2020 Paper 2 Variant 2, question 6.

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