Water from natural sources contains dissolved substances which are not pollutants, such as mineral salts.
- (a)Name another substance found naturally in water which is not a mineral salt or a pollutant.[1]
- (b)When lithium reacts with water, aqueous lithium hydroxide, LiOH, and hydrogen are formed. Construct the equation for this reaction.[1]
- (c)(i)Sodium and potassium react with water in a similar way to lithium. Explain, in terms of their electronic configuration, why lithium, sodium and potassium all react in a similar way.[1]
- (c)(ii)Describe the trend in reactivity of the Group I elements lithium, sodium and potassium.[1]
- (d)Water and oxygen are formed when aqueous hydrogen peroxide decomposes. 2H2O2(aq) → 2H2O(l) + O2(g) Calculate the maximum volume of oxygen, at room temperature and pressure, which is produced by the complete decomposition of a solution containing 16.0g of hydrogen peroxide. Give your answer to three significant figures. volume of oxygen .................................................... dm³[3]
- (e)(i)A fuel cell generates electricity when hydrogen and oxygen react on platinum electrodes. Name a process used in industry to produce hydrogen.[1]
- (e)(ii)Some cars use a hydrogen–oxygen fuel cell instead of a petrol (gasoline) engine as a source of energy. Describe two advantages of a hydrogen–oxygen fuel cell compared with a petrol (gasoline) engine. 1. 2.[2]
Mark scheme
Marking points from the official mark scheme (Oct/Nov 2020). The mark or mark type is shown in brackets.
- [1] 4(a) oxygen
- [1] 4(b) 2Li + 2H2O → 2LiOH + H2
- [1] 4(c)(i) all have one electron in their outer shell
- [1] 4(c)(ii) increases down the Group ORA
- [1] 4(d) mol hydrogen peroxide = 16 / 34 OR 0.471 (1)
- [1] 4(d) mol oxygen = 0.471 / 2 OR 0.235 (1)
- [1] 4(d) volume of oxygen = 5.65 (dm³) (1)
- [1] 4(e)(i) cracking (hydrocarbons) / electrolysis (of water)
- [1] 4(e)(ii) any two from: • water is only product / no other product than water • no pollutants made / no harmful exhaust fumes / no harmful gas made • greater efficiency / less heat loss / more energy per gram of fuel • (hydrogen is) renewable source of fuel / uses renewable source of fuel / uses renewable source of energy
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