Proteins are natural polymers.
- (a)Name one other natural polymer.[1]
- (b)Describe how proteins can be hydrolysed to amino acids.[2]
- (c)The structure of the amino acid alanine is shown. H | H2N-C - COOH | CH3 Alanine can be polymerised to form poly(alanine). Draw the partial structure of poly(alanine) to show two repeat units.[2]
- (d)The structure of the amino acid serine is shown. H | H2N-C - COOH | CH2OH Serine can form polymers with amide linkages. Serine can also form polymers with a different linkage. Name this linkage and explain how it is formed. linkage explanation[2]
- (e)(i)Paper chromatography can be used to separate a mixture of amino acids. The apparatus used is shown. [Diagram: lid, chromatography paper, baseline, solvent] Why should the baseline be drawn in pencil and not in ink?[1]
- (e)(ii)When the separation of the amino acids is complete, the chromatography paper is sprayed with a locating agent. Explain why.[1]
- (e)(iii)The diagram shows the chromatography paper after it has been sprayed with a locating agent. [Diagram: solvent front, S spot, baseline] Calculate the R_f_ value of the amino acid labelled S.[1]
This question uses a diagram from the original paper, which isn't shown here. Open the full paper from the past papers archive to see it.
Mark scheme
Marking points from the official mark scheme (Oct/Nov 2019). The mark or mark type is shown in brackets.
- [1] complex carbohydrates / starch / polysaccharides
- [1] heat / reflux
- [1] with hydrochloric acid
- [2] minimum of two correct repeat units with amide link and extension bonds [Structure: -NH-CH(CH3)-CO-NH-CH(CH3)-CO-]
- [1] If 2 marks not scored 1 mark for continuation bonds and one amide link
- [1] ester (linkage)
- [1] OH and COOH / alcohol and carboxylic acid
- [1] ink will run / ink will undergo chromatography / pencil will not run / pencil will not move during chromatography / ink will separate / pencil will not separate
- [1] to make the spots visible / coloured
- [1] 0.71
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