This question is about polymers.
- (a)Polyesters and polyamides are both polymers formed by condensation reactions. What is meant by the term condensation reaction?[1]
- (b)The partial structure of a polyester is shown. [Figure: Partial structure of a polyester: -[O-C(=O)-CH₂-CH₂-C(=O)-O-CH₂-CH₂]-]
- (b)(i)On the diagram, draw a circle around an ester linkage.[1]
- (b)(ii)Draw the structures of the two monomers used to produce this polymer.[2]
- (b)(iii)Terylene is a polyester. State one common use of Terylene.[1]
- (c)The structure of the amino acid threonine is shown. H H2N–C–COOH H–C–OH CH3 Threonine can be polymerised. Explain, by referring to the groups present, why polymers with different linkages can be formed from threonine.[2]
- (d)Poly(ethene) is made from ethene monomers.
- (d)(i)Draw the structure of ethene, showing all of the atoms and all of the bonds.[1]
- (d)(ii)Poly(ethene) is a non-biodegradable plastic. What is meant by the term non-biodegradable?[1]
- (d)(iii)Describe one pollution problem caused by the disposal of non-biodegradable plastics.[1]
This question uses a diagram from the original paper, which isn't shown here. Open the full paper from the past papers archive to see it.
Mark scheme
Marking points from the official mark scheme (Oct/Nov 2019). The mark or mark type is shown in brackets.
- 9(a) reaction in which molecules combine and small molecule is formed
- 9(b)(i) circle drawn around one of the COO linkage
- 9(b)(ii) HOOC-◻-COOH (1)
- HO-◻-OH (1)
- 9(b)(iii) clothing / fabrics
- 9(c) amide link can form between NH2 and COOH (1)
- ester link can form between OH and COOH (1)
- 9(d)(i) H H / C=C / H H
- 9(d)(ii) cannot be broken down (by organisms) / cannot be broken by biological means / cannot be decomposed (by bacteria) / cannot be decayed (by fungi)
- 9(d)(iii) gets stuck in gullets of birds / gets stuck in gills of fish / blocks drains / litter / burning causes toxic gases to be emitted / burning causes greenhouse gas emissions
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