Silicon is an element in Group IV of the Periodic Table.
- (a)One of the isotopes of silicon is: 30 14 Si Deduce the number of electrons, neutrons and protons in one atom of this isotope of silicon. number of electrons .................................................................................................................... number of neutrons .................................................................................................................... number of protons .................................................................................................................... [3][3]
- (b)Silicon reacts with nitrogen when heated to produce silicon nitride, Si3N4. Construct the equation for this reaction.[1]
- (c)The structure of silicon dioxide is shown. silicon atom oxygen atom [Figure: Ball-and-stick model of silicon dioxide lattice structure, with black spheres for silicon and white spheres for oxygen]
- (c)(i)Describe two similarities in the structures of silicon dioxide and diamond. 1 ..................................................................................................................................................... 2 ..................................................................................................................................................... [2][2]
- (c)(ii)Explain why silicon dioxide has a high melting point.[2]
- (d)The structure of a compound of silicon is shown. H HH O HH H–C–C—Si—C–C–H HH O HH H Deduce the molecular formula of this compound.[1]
- (e)Draw a 'dot-and-cross' diagram for a silicon(IV) chloride molecule, SiCl4. Only include the outer shell electrons.[1]
This question uses a diagram from the original paper, which isn't shown here. Open the full paper from the past papers archive to see it.
Mark scheme
Marking points from the official mark scheme (Oct/Nov 2019). The mark or mark type is shown in brackets.
- 8(a) electrons: 14 (1)
- neutrons: 16 (1)
- protons: 14 (1)
- 8(b) 3Si + 2N2 → Si3N4
- 8(c)(i) Any two from:
- both have covalent bonds / covalent (lattice) (1)
- both have giant structures (1)
- tetrahedral arrangement of structure (1)
- 8(c)(ii) many strong bonds / strong bonding throughout the structure (1)
- needs a high temperature to break (all) the bonds / needs a lot of energy to break (all) the bonds (1)
- 8(d) SiO2C4H12
- 8(e) pair of shared electrons between each of the 4 Cl atoms and central Si AND 6 non-bonding electrons around each chlorine
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