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O-LevelChemistryBonding & Structure5070/21 · Oct/Nov 2019 · Q58 Marks

The table shows some properties of four Group VII elements. element melting point in °C boiling point in °C density of liquid at boiling point in g/cm³ colour chlorine −101 −35 light green bromine −7 3.12 red-brown iodine 114 184 4.93 grey-black astatine 302 337 6.35

  1. (a)(i)Complete the table by estimating : the boiling point of bromine the density of liquid chlorine at its boiling point.[2]
  2. (a)(ii)Use the information in the table to suggest the colour of astatine.[1]
  3. (b)Explain why chlorine is used in water treatment.[1]
  4. (c)Chlorine reacts with aqueous potassium iodide. The products are aqueous potassium chloride and aqueous iodine.
  5. (c)(i)Construct the ionic equation for this reaction.[1]
  6. (c)(ii)Explain why potassium chloride does not react with iodine.[1]
  7. (d)Hydrated nickel(II) chloride has the formula NiCl2.xH2O. It has a relative formula mass of 238. Calculate the value of x in this formula. [The relative atomic mass of nickel, Ni, is 59] X = .......................................................................................... [2][2]

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Mark scheme

Marking points from the official mark scheme (Oct/Nov 2019). The mark or mark type is shown in brackets.

  1. 5(a)(i) boiling point of bromine: values between -10 and 150 °C (inclusive) (1)
  2. density of liquid chlorine: values between 1 and 3 (inclusive) (1)
  3. 5(a)(ii) black / grey-black / purple-grey / purple-black
  4. 5(b) kills bacteria / disinfects the water
  5. 5(c)(i) Cl2 + 2I- → 2Cl- + I2
  6. 5(c)(ii) chlorine is more reactive than iodine / chlorine is a stronger oxidising agent than iodine / ORA
  7. 5(d) molar mass of NiCl2 = 130 (1)
  8. x = 6 (1)

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About this question

Topic
Bonding & Structure, O-Level Chemistry (syllabus 5070). Structured question, 8 marks.
Source
O-Level Chemistry, Oct/Nov 2019 Paper 2 Variant 1, question 5.

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