B9 Cyclopropane is converted to propene when heated. [Figure 18.1: Diagram showing cyclopropane (H₂C-CH₂-CH₂) converting to propene (CH₃CH=CH₂)]
- (a)Explain why cyclopropane and propene are isomers.[1]
- (b)The graph shows how the concentration of propene in this reaction changes with time. [Figure 18.2: Graph showing concentration of propene in mol/dm³ versus time/min. The curve starts at 0, increases rapidly then gradually slows down, eventually leveling off.] Describe how the rate of this reaction changes with time. Explain your answer by referring to the graph.[2]
- (c)Describe and explain the effect of increasing the concentration of cyclopropane on the rate of this reaction.[2]
- (d)Describe and explain the effect of decreasing the temperature on the rate of this reaction.[2]
- (e)Propene undergoes addition reactions. Two addition reactions of propene are shown in the diagram. Complete the diagram to show the missing name, formula and conditions. [Figure 19.1: Reaction diagram showing propene (CH₃CH=CH₂) undergoing two addition reactions. One reaction is with +steam, leading to a product where 'name' and 'formula' are missing. The other reaction is with +H₂, leading to propane (CH₃CH₂CH₃), where 'conditions 1' and 'conditions 2' are missing.][3]
This question uses a diagram from the original paper, which isn't shown here. Open the full paper from the past papers archive to see it.
Mark scheme
Marking points from the official mark scheme (Oct/Nov 2017). The mark or mark type is shown in brackets.
- [1] B9(a) they have the same molecular formula but the atoms are arranged differently
- [1] B9(b) rate decreases
- [1] B9(b) the gradient of the graph decreases / slope of the graph decreases
- [0] B9(c) increases rate (no marks)
- [1] B9(c) particles closer together / more particles in a given volume / more crowded particles
- [1] B9(c) greater collision frequency / more collisions per second / rate of collisions increases
- [0] B9(d) decreases rate (no marks)
- [1] B9(d) particles move more slowly / particles have less kinetic energy
- [1] B9(d) number of particles with energy equal to or greater than the activation energy is decreased / fewer successful collisions / fewer effective collisions
- [1] B9(e) left hand box: propanol
- [1] B9(e) left hand box: C3H7OH
- [1] B9(e) right hand conditions: catalyst / Ni AND heat / high temperature / high pressure
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