A student set up a tube as shown in the diagram. [Figure A5.1: Diagram showing a long horizontal tube with cotton wool soaked in hydrobromic acid at the left end, and cotton wool soaked in aqueous ammonia at the right end. A point X is marked closer to the hydrobromic acid end.] Concentrated hydrobromic acid produces fumes of hydrogen bromide. Concentrated aqueous ammonia produces fumes of ammonia.
- (a)After some time, solid ammonium bromide appeared on the walls of the tube at point X. Use the kinetic particle theory to explain this result.[4]
- (b)A gas syringe is filled with 70cm³ of ammonia gas. The pressure on the plunger is increased. The temperature does not change but the volume in the syringe decreases to 60 cm³. [Figure A5.2: Diagram of a gas syringe. Initial volume 70 cm³ with plunger up, final volume 60 cm³ with plunger pushed down. Ammonia gas is inside.] Use the kinetic particle theory to explain why the volume decreases.[1]
This question uses a diagram from the original paper, which isn't shown here. Open the full paper from the past papers archive to see it.
Mark scheme
Marking points from the official mark scheme (Oct/Nov 2015). The mark or mark type is shown in brackets.
- [4] A5 (a) (i) ANY FOUR FROM: ammonia molecules/HBr molecules have enough energy to escape from the HBr(aq) or NH3(aq) (1) diffusion (1) molecules move randomly/molecules spread out/molecules get mixed up (1) move from high to low concentration/move with the concentration gradient (1) solid formed where NH3 and HBr react (1) HBr has higher Mᵣ than NH3/molecules of HBr are heavier than molecules of NH3 (1) NH3 molecules move faster than HBr molecules/NH3 diffuses faster (1)
- [1] (b) higher pressure pushes molecules closer together
Write your answer and get it marked
On Oracle Prep you can write or photograph your own answer and have it marked by AI against this mark scheme, with feedback on what you missed.
Sign up free →