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O-LevelChemistryAcids, Bases & Salts5070/22 · Oct/Nov 2014 · Q19 Marks

The diagram shows part of the Periodic Table. Only some of the elements are shown. H C N F Si P S Cl Ti Fe Cu Zn As Br

  1. (a)(i)is a simple molecular solid at room temperature and pressure,[1]
  2. (a)(ii)oxidises in the presence of water and air to form rust,[1]
  3. (a)(iii)has an atom with three occupied electron shells, the outer of which has only 5 electrons,[1]
  4. (a)(iv)has an oxide which is amphoteric,[1]
  5. (a)(v)has a chloride of type XCl3 whose aqueous solution forms a reddish-brown precipitate on addition of aqueous ammonia,[1]
  6. (a)(vi)is a colourless diatomic gas.[1]
  7. (b)(i)Arsenic reacts with oxygen to form arsenic(III) oxide, As2O3. Construct the equation for this reaction.[1]
  8. (b)(ii)Arsenic(III) oxide is slightly soluble in water. A weak acid, arsenous acid, H3AsO3, is formed. Use kinetic particle theory to explain why a 0.05mol/dm³ solution of arsenous acid reacts much more slowly with magnesium ribbon than a 0.05mol/dm³ solution of hydrochloric acid.[2]

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Mark scheme

Marking points from the official mark scheme (Oct/Nov 2014). The mark or mark type is shown in brackets.

  1. [1] A1 (a) (i) S/sulfur/P/phosphorus (1)
  2. [1] A1 (a) (ii) Fe/iron (1)
  3. [1] A1 (a) (iii) P/phosphorus (1)
  4. [1] A1 (a) (iv) Zn/zinc/As/arsenic (1)
  5. [1] A1 (a) (v) Fe/iron (1)
  6. [1] A1 (a) (vi) H/hydrogen/H2/N/nitrogen/N2 (1)
  7. [1] A1 (b) (i) 4As + 3O2 → 2As2O3 (1)
  8. [1] A1 (b) (ii) (arsenous acid) has a lower concentration of hydrogen ions/hydrochloric acid has higher concentration of hydrogen ions (1)
  9. [1] A1 (b) (ii) less frequent collisions (between ions in arsenous acid)/more frequent collisions (between ions) in hydrochloric acid (1)

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About this question

Topic
Acids, Bases & Salts, O-Level Chemistry (syllabus 5070). Structured question, 9 marks.
Source
O-Level Chemistry, Oct/Nov 2014 Paper 2 Variant 2, question 1.

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