The diagram shows part of the Periodic Table. Only some of the elements are shown. H C N F Si P S Cl Ti Fe Cu Zn As Br
- (a)(i)is a simple molecular solid at room temperature and pressure,[1]
- (a)(ii)oxidises in the presence of water and air to form rust,[1]
- (a)(iii)has an atom with three occupied electron shells, the outer of which has only 5 electrons,[1]
- (a)(iv)has an oxide which is amphoteric,[1]
- (a)(v)has a chloride of type XCl3 whose aqueous solution forms a reddish-brown precipitate on addition of aqueous ammonia,[1]
- (a)(vi)is a colourless diatomic gas.[1]
- (b)(i)Arsenic reacts with oxygen to form arsenic(III) oxide, As2O3. Construct the equation for this reaction.[1]
- (b)(ii)Arsenic(III) oxide is slightly soluble in water. A weak acid, arsenous acid, H3AsO3, is formed. Use kinetic particle theory to explain why a 0.05mol/dm³ solution of arsenous acid reacts much more slowly with magnesium ribbon than a 0.05mol/dm³ solution of hydrochloric acid.[2]
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Mark scheme
Marking points from the official mark scheme (Oct/Nov 2014). The mark or mark type is shown in brackets.
- [1] A1 (a) (i) S/sulfur/P/phosphorus (1)
- [1] A1 (a) (ii) Fe/iron (1)
- [1] A1 (a) (iii) P/phosphorus (1)
- [1] A1 (a) (iv) Zn/zinc/As/arsenic (1)
- [1] A1 (a) (v) Fe/iron (1)
- [1] A1 (a) (vi) H/hydrogen/H2/N/nitrogen/N2 (1)
- [1] A1 (b) (i) 4As + 3O2 → 2As2O3 (1)
- [1] A1 (b) (ii) (arsenous acid) has a lower concentration of hydrogen ions/hydrochloric acid has higher concentration of hydrogen ions (1)
- [1] A1 (b) (ii) less frequent collisions (between ions in arsenous acid)/more frequent collisions (between ions) in hydrochloric acid (1)
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