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O-LevelChemistryElectrolysis5070/21 · Oct/Nov 2014 · Q49 Marks

The diagram shows a simple electrochemical cell. [Figure of a simple electrochemical cell showing a V voltmeter connected to a positive electrode and a negative electrode, both immersed in dilute sulfuric acid.] The voltages produced by different combinations of metal electrodes are shown in the table below. The more reactive metal is always the negative electrode. | positive electrode | negative electrode | voltage/V | |:-------------------|:-------------------|:----------| | copper | zinc | 1.10 | | copper | tin | 0.48 | | copper | magnesium | 2.70 | | copper | iron | 0.78 | | silver | copper | 0.46 |

  1. (a)(i)Write an equation showing the conversion of zinc to zinc ions.[1]
  2. (a)(ii)How does the table above show that copper is above silver in the reactivity series?[1]
  3. (a)(iii)Which combination of metals in the table above will give the highest voltage?[1]
  4. (a)(iv)Use the information in the table to deduce the order of reactivity of the metals copper, iron, magnesium, tin and zinc. Explain your answer. most reactive least reactive[2]
  5. (b)Refer to the structure of metals to explain
  6. (b)(i)why metals are malleable,[2]
  7. (b)(ii)why metals conduct electricity.[1]
  8. (c)Explain why plating iron with tin prevents the iron from rusting.[1]

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Mark scheme

Marking points from the official mark scheme (Oct/Nov 2014). The mark or mark type is shown in brackets.

  1. [1] (a)(i) Zn → Zn²⁺ + 2e¯ / Zn – 2e¯ → Zn²⁺ (1)
  2. [1] (a)(ii) in the copper/silver cell the copper is the negative electrode (1)
  3. [1] (a)(iii) silver and magnesium (1)
  4. [2] (a)(iv) magnesium zinc iron tin copper (1) the higher the voltage (difference between copper and the metal) the more reactive the metal/voltage (difference) gets smaller, the less reactive the metal (1)
  5. [2] (b)(i) metal layers (1) slide over each other when force applied (1)
  6. [1] (b)(ii) electrons (originating from valency shell) can move/sea of electrons/some of the electrons are mobile/there are free electrons (1)
  7. [1] (c) tin prevents oxygen and/or water from reaching the iron (1)

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About this question

Topic
Electrolysis, O-Level Chemistry (syllabus 5070). Structured question, 9 marks.
Source
O-Level Chemistry, Oct/Nov 2014 Paper 2 Variant 1, question 4.

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