A student investigates solution W and solid X.
- (a)(i)Solution W is green in colour and contains Fe²⁺ ions. Describe how W can be shown to contain Fe²⁺ ions.[2]
- (a)(ii)Excess W is added to acidified aqueous potassium manganate(VII). Describe the colour change seen. from .............................................................. to ..............................................................[2]
- (a)(iii)Describe the observations made when a few drops of aqueous ammonia and then an excess of aqueous ammonia are added to the mixture from (ii). a few drops .................................................................................................................... an excess .....................................................................................................................[2]
- (b)(i)Solid X is a shiny grey metal. The tests the student does on X are shown in Table 3.1. Some of the observations for these tests are also shown. [Table 3.1: tests on solid X and observations] Predict the identity of the gas produced in test 1. Describe how the student tests the gas to confirm its identity. gas .............................................................................................................................. test .............................................................................................................................. observation to confirm gas ............................................................................................[3]
- (b)(ii)The observations for test 1 are incomplete. State one other observation that the student makes for test 1.[1]
- (b)(iii)State the conclusion you can make from test 2.[1]
- (b)(iv)State the conclusion you can make from test 3.[1]
- (b)(v)Identify the acid used in test 1.[1]
- (b)(vi)Suggest the identity of metal X.[1]
Mark scheme
Marking points from the official mark scheme (May/June 2023). The mark or mark type is shown in brackets.
- [1] (a)(i) M1 add sodium hydroxide / aqueous ammonia.
- [1] (a)(i) M2 Green ppt insoluble in excess
- [1] (a)(ii) M1 purple
- [1] (a)(ii) M2 yellow
- [1] (a)(iii) M1 (red-) brown precipitate
- [1] (a)(iii) M2 insoluble in excess
- [1] (b)(i) M1 hydrogen
- [1] (b)(i) M2 burning splint
- [1] (b)(i) M3 pop sound
- [1] (b)(ii) effervescence
- [1] (b)(iii) there are no halide ions present
- [1] (b)(iv) sulfate / SO4²⁻ ions are present
- [1] (b)(v) sulfuric acid / H2SO4
- [1] (b)(vi) magnesium / zinc
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