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O-LevelChemistryAcids, Bases & Salts5070/41 · May/June 2023 · Q314 Marks

A student investigates solution W and copper(II) carbonate. (a) The tests the student does on W are shown in Table 3.1. Some of the observations for these tests are also shown. Table 3.1 tests on solution W observations 1 Add aqueous sodium hydroxide to W. solution remains colourless 2 Add dilute nitric acid, then add aqueous barium nitrate to W. white precipitate 3 Add dilute hydrochloric acid, then add aqueous silver nitrate to W. white precipitate 4 Flame test on W. no colour is observed

  1. (a)(i)The student correctly concludes that ammonia is formed in test 1. Describe what else the student must have done to reach this conclusion.[3]
  2. (a)(ii)State why the student cannot identify the anion in W from the observation in test 3.[1]
  3. (a)(iii)State how the tests and observations show that W does not contain sodium ions.[1]
  4. (a)(iv)Identify the cation and anion in W. cation ..................................................... anion .....................................................[2]
  5. (b)(i)The student adds dilute hydrochloric acid to copper(II) carbonate. A gas and a solution are produced. State the observation that confirms the production of a gas.[1]
  6. (b)(ii)Describe how to do a flame test to confirm the presence of copper(II) ions in the solution.[3]
  7. (b)(iii)Describe one other method the student could use to confirm that the solution contains copper(II) ions.[3]

Mark scheme

Marking points from the official mark scheme (May/June 2023). The mark or mark type is shown in brackets.

  1. [1] M1 warm
  2. [1] M2 test gas with (damp red) litmus paper
  3. [1] M3 paper turns blue
  4. [1] hydrochloric acid contains chloride / Cl⁻ ions
  5. [1] sodium ions would give a yellow flame
  6. [1] M1 ammonium / NH₄⁺
  7. [1] M2 sulfate / SO₄²⁻
  8. [1] effervescence
  9. [1] M1 any workable method to introduce solution into flame
  10. [1] M2 blue flame of Bunsen
  11. [1] M3 flame changes colour to blue / green / blue-green
  12. [1] M1 (aqueous) sodium hydroxide
  13. [1] M2 blue ppt
  14. [1] M3 insoluble in excess
  15. [1] M1 (aqueous) ammonia
  16. [1] M2 blue ppt
  17. [1] M3 dark blue solution in excess

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About this question

Topic
Acids, Bases & Salts, O-Level Chemistry (syllabus 5070). Structured question, 14 marks.
Source
O-Level Chemistry, May/June 2023 Paper 4 Variant 1, question 3.

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