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O-LevelChemistryRates of Reaction5070/22 · May/June 2023 · Q68 Marks

This question is about the energy changes that take place during chemical reactions. (a) Nitrogen reacts with oxygen to make nitrogen monoxide. The reaction is endothermic. N₂(g) + O₂(g) → 2NO(g) Draw, on the axes provided in Fig. 6.1, the reaction pathway diagram for this reaction. Include labels for the: • axes • reactants • product • enthalpy change of reaction, ΔH • activation energy, Ea [Figure 6.1]

  1. (a)Nitrogen reacts with oxygen to make nitrogen monoxide. The reaction is endothermic. N₂(g) + O₂(g) → 2NO(g) Draw, on the axes provided in Fig. 6.1, the reaction pathway diagram for this reaction. Include labels for the: • axes • reactants • product • enthalpy change of reaction, ΔH • activation energy, Ea[5]
  2. (b)Hydrogen reacts with bromine to make hydrogen bromide. H—H + Br—Br → 2H—Br Calculate the enthalpy change of this reaction. Use the bond energies in Table 6.1. [Table 6.1] enthalpy change of reaction[3]

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Mark scheme

Marking points from the official mark scheme (May/June 2023). The mark or mark type is shown in brackets.

  1. 6(a) correct labels for axes (1)
  2. reactants on a line (1)
  3. product on a line to the right and above reactant line (1)
  4. vertical line with arrow and correct label for enthalpy change (1)
  5. vertical line with arrow and correct label for activation energy (1)
  6. 6(b) energy associated with bond breaking = 436 + 193 OR 629 (1)
  7. energy associated with bond forming = 2 × 366 OR 732 (1)
  8. (enthalpy change = 629 – 732) = –103 (kJ/mol)

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About this question

Topic
Rates of Reaction, O-Level Chemistry (syllabus 5070). Structured question, 8 marks.
Source
O-Level Chemistry, May/June 2023 Paper 2 Variant 2, question 6.

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