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A-LevelChemistryChemical bonding9701/21 · May/June 2019 · Q215 Marks

Magnesium silicide, Mg₂Si, is a compound made by heating magnesium with sand.

  1. (a)Draw a 'dot-and-cross' diagram to show the arrangement of outer electrons present in a formula unit of Mg2Si. Assume magnesium silicide is an ionic compound.[2]
  2. (b)When solid Mg2Si is added to water, silane gas, SiH4, and a solution of magnesium hydroxide are produced. Construct the equation for this reaction. Include state symbols.[2]
  3. (c)Suggest, with reference to structure and bonding, why SiH4 is a gas at room temperature.[2]
  4. (d)(i)C-H and Si–H bonds have weak dipoles. Use the electronegativity values in the table to show the polarity of the C-H and Si-H bonds. C-H Si-H[2]
  5. (d)(ii)Explain why methane, CH4, has no overall dipole moment.[2]
  6. (e)SiH4 reacts in air without heating but CH4 must be ignited before combustion occurs. SiH4 + 2O2 → SiO2 + 2H2O CH4 + 2O2 → CO2 + 2H2O Suggest, with reference to bond energies from the Data Booklet, why SiH4 reacts in air without heating but CH4 must be ignited.[2]
  7. (f)(i)Identify the two products formed during this reaction.[2]
  8. (f)(ii)Describe the behaviour of the silicon dioxide during this reaction.[1]

Mark scheme

Marking points from the official mark scheme (May/June 2019). The mark or mark type is shown in brackets.

  1. [1] M1 magnesium: +2 charge on two Mg AND both with 0 or 8 electrons
  2. [1] M2 silicide: -4 charge on one Si and 8 electrons
  3. [1] M1 correct balancing and formulae
  4. [1] M2 state symbols
  5. [1] M1 simple (covalent) / molecular / molecules
  6. [1] M2 weak IMF / (temporary) induced dipole (forces)
  7. [1] Cδ--Hδ+
  8. [1] Siδ+-Hδ-
  9. [1] M1 tetrahedral (molecule)
  10. [1] M2 (so individual bond) dipoles / partial charges cancel
  11. [1] M1 Si-H bond is (much) weaker than C-H bond
  12. [1] M2 low activation energy ORA
  13. [1] M1 sodium silicate / Na2SiO3
  14. [1] M2 water / H2O
  15. [1] acid(ic)

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About this question

Topic
Chemical bonding, A-Level Chemistry (syllabus 9701). Structured question, 15 marks.
Source
A-Level Chemistry, May/June 2019 Paper 2 Variant 1, question 2.

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