Magnesium silicide, Mg₂Si, is a compound made by heating magnesium with sand.
- (a)Draw a 'dot-and-cross' diagram to show the arrangement of outer electrons present in a formula unit of Mg2Si. Assume magnesium silicide is an ionic compound.[2]
- (b)When solid Mg2Si is added to water, silane gas, SiH4, and a solution of magnesium hydroxide are produced. Construct the equation for this reaction. Include state symbols.[2]
- (c)Suggest, with reference to structure and bonding, why SiH4 is a gas at room temperature.[2]
- (d)(i)C-H and Si–H bonds have weak dipoles. Use the electronegativity values in the table to show the polarity of the C-H and Si-H bonds. C-H Si-H[2]
- (d)(ii)Explain why methane, CH4, has no overall dipole moment.[2]
- (e)SiH4 reacts in air without heating but CH4 must be ignited before combustion occurs. SiH4 + 2O2 → SiO2 + 2H2O CH4 + 2O2 → CO2 + 2H2O Suggest, with reference to bond energies from the Data Booklet, why SiH4 reacts in air without heating but CH4 must be ignited.[2]
- (f)(i)Identify the two products formed during this reaction.[2]
- (f)(ii)Describe the behaviour of the silicon dioxide during this reaction.[1]
Mark scheme
Marking points from the official mark scheme (May/June 2019). The mark or mark type is shown in brackets.
- [1] M1 magnesium: +2 charge on two Mg AND both with 0 or 8 electrons
- [1] M2 silicide: -4 charge on one Si and 8 electrons
- [1] M1 correct balancing and formulae
- [1] M2 state symbols
- [1] M1 simple (covalent) / molecular / molecules
- [1] M2 weak IMF / (temporary) induced dipole (forces)
- [1] Cδ--Hδ+
- [1] Siδ+-Hδ-
- [1] M1 tetrahedral (molecule)
- [1] M2 (so individual bond) dipoles / partial charges cancel
- [1] M1 Si-H bond is (much) weaker than C-H bond
- [1] M2 low activation energy ORA
- [1] M1 sodium silicate / Na2SiO3
- [1] M2 water / H2O
- [1] acid(ic)
Write your answer and get it marked
On Oracle Prep you can write or photograph your own answer and have it marked by AI against this mark scheme, with feedback on what you missed.
Sign up free →