The most common oxidation states of cobalt are +2 and +3. Complete the electronic configurations of the following free ions. • Co2+ [Ar] • Co³+ [Ar]
- (a)The most common oxidation states of cobalt are +2 and +3. Complete the electronic configurations of the following free ions. • Co2+ [Ar] • Co³+ [Ar][1]
- (b)Co2+ and Co³+ both form complexes with edta⁴-. half-equation E°/V Co3+ + e- ⇌ Co2+ +1.82 O2 + 4H+ + 4e¯ ⇌ 2H₂O +1.23 [Co(edta)] + e¯ ⇌ [Co(edta)]2- +0.38 Co2+ + 2e- ⇌ Co -0.28 Use the data in the table to predict what happens, if anything, when separate aqueous solutions of Co³+ and [Co(edta)] are left to stand in the air. aqueous solution of Co³+ aqueous solution of [Co(edta)]-[3]
- (c)Hydrated cobalt(II) nitrate, Co(NO3)2•6H2O, is a red solid that behaves like hydrated magnesium nitrate, Mg(NO3)2•6H₂O, when heated. Describe in detail what you would expect to observe when crystals of Co(NO3)2•6H2O are heated in a boiling tube, gently at first and then more strongly.[2]
- (d)Explain why the thermal stability of the Group 2 nitrates increases down the group.[2]
This question uses a diagram from the original paper, which isn't shown here. Open the full paper from the past papers archive to see it.
Mark scheme
Marking points from the official mark scheme (Feb/Mar 2021). The mark or mark type is shown in brackets.
- [1] Co2+ = [Ar] 3d7 (4s°); Co3+ = [Ar] 3d6 (4s°)
- [3] M1/2: (for Co3+ solution) Co3+ is reduced to Co2+; oxygen gas/O2 is evolved; E of Co3+ greater than E of O2 (any two for 2 marks)
- [3] M3: (for [Co(edta)]- solution) no change (to [Co(edta)]¯) / not feasible OWTTE
- [2] condensation on tube / steam evolved; brown fumes / brown gas evolved; O2 formed that relights a glowing splint; (solid) dissolves / turns to liquid (any two visual observations)
- [2] M1: cationic radius / ion size increases (down the group)
- [2] M2: less polarisation / distortion of nitrate ion / anion / NO3-
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