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A-LevelChemistryChemical periodicity9701/22 · Oct/Nov 2025 · Q220 Marks

The Period 3 elements show trends in physical and chemical properties across the period.

  1. (a)(i)Explain why the elements Na to Al are good electrical conductors.[1]
  2. (a)(ii)Explain why the elements P, S and Cl do not conduct electricity.[1]
  3. (b)Fig. 2.1 shows the variation in melting point of the Period 3 elements Si to Cl. [Figure 2.1] The Period 3 elements Si to Cl are all non-metals. Explain why there is a large difference between the melting point of Si and the melting points of P, S and Cl.[2]
  4. (c)Table 2.1 gives some information about some Period 3 chlorides. Row B refers to the pH of the solution that forms when the Period 3 chloride is added to water. [Table 2.1] Complete Table 2.1. You may use the following abbreviations. I = ionic, C = covalent, M = metallic G = giant, S = simple[4]
  5. (d)(i)Write an equation for the formation of AlCl₃ from its elements.[1]
  6. (d)(ii)Write an equation for the formation of H₃PO₄ from PCl₅.[1]
  7. (e)(i)S₂Cl₂(l) reacts with Cl₂(g) in a reversible reaction to form SCl₂(l). Under certain conditions, a dynamic equilibrium is established. S₂Cl₂(l) + Cl₂(g) ⇌ 2SCl₂(l) ΔH = −41 kJ mol⁻¹ State what is meant by dynamic equilibrium.[1]
  8. (e)(ii)Identify the condition necessary to establish dynamic equilibrium.[1]
  9. (e)(iii)S₂Cl₂(l) is yellow and SCl₂(l) is red. S₂Cl₂(l) + Cl₂(g) ⇌ 2SCl₂(l) ΔH = −41 kJ mol⁻¹ State what is observed when the following changes are made to an equilibrium mixture of S₂Cl₂(l) and SCl₂(l). Explain your answers. • The equilibrium mixture is warmed gently. observation explanation • The overall pressure of the equilibrium mixture is increased. observation explanation[4]
  10. (f)(i)Aqueous MgCl₂ reacts with aqueous Na₂CO₃ to form a white precipitate. Upon heating, the white precipitate undergoes thermal decomposition. Construct an equation to show the reaction of aqueous MgCl₂ with aqueous Na₂CO₃. Use state symbols in your equation.[2]
  11. (f)(ii)Identify the products of the thermal decomposition of the white precipitate.[1]
  12. (f)(iii)State the trend in thermal stability of the Group 2 carbonates down the group.[1]

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Mark scheme

Marking points from the official mark scheme (Oct/Nov 2025). The mark or mark type is shown in brackets.

  1. [1] delocalised electrons move (through the structure / between layers)
  2. [1] P/S/Cl have no charge carriers OR (no ions and) no delocalised electrons OR no mobile / moving ions
  3. [2] M1 Si has (lots of) strong covalent bonds broken M2 P/S/Cl (only) has weak Van der Waals' (forces) broken
  4. [4] M1 +1 +2 +3 +4 +5 M2 7 6.5 0-4 0-4 0-4 M3 I I I C C M4 G G G S S
  5. [1] 2Al + 3Cl₂ → 2AlCl₃
  6. [1] PCl₅ + 4H₂O → H₃PO₄ + 5HCl
  7. [1] rate of forward and backward (reaction) are the same / equal OR (ratio of) concentrations of reactants and products are constant
  8. [1] closed system
  9. [4] M1 (mixture / solution becomes more) yellow M2 (forward) reaction is exothermic (equilibrium shifts left) OR equilibrium/reaction shifts (left) to absorb (additional) heat / energy M3 (mixture / solution becomes more) red M4 fewer moles of gas on right-hand side OR (gas on left and) no gas on the right
  10. [2] M1 formulae in balanced equation M2 state symbols MgCl₂(aq) + Na₂CO₃(aq) → MgCO₃(s) + 2NaCl(aq)
  11. [1] MgO / magnesium oxide AND CO₂ / carbon dioxide
  12. [1] (thermal stability) increases (down the group)

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About this question

Topic
Chemical periodicity, A-Level Chemistry (syllabus 9701). Structured question, 20 marks.
Source
A-Level Chemistry, Oct/Nov 2025 Paper 2 Variant 2, question 2.

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