The Period 3 elements show trends in physical and chemical properties across the period. Fig. 2.1 shows the variation in atomic and ionic radii of the Period 3 elements Na to Cl. The ionic radius of Si is not shown. [Figure 2.1]
- (a)(i)Explain the trend shown in the atomic radii of the Period 3 elements Na to Cl.[2]
- (a)(ii)Explain why there is a large difference in the ionic radii of Al and P.[2]
- (b)Table 2.1 gives some information about some of the Period 3 oxides. Row B gives the pH of the solution that forms when the Period 3 oxide is added to water. [Table 2.1]
- (b)(i)Complete Table 2.1.[2]
- (b)(ii)State why there is no data given in row B for Al₂O₃ and SiO₂.[1]
- (c)(i)Write an equation for the reaction of Na₂O with dilute hydrochloric acid.[1]
- (c)(ii)Construct an equation for the reaction of Al₂O₃ with a base to form NaAlO₂.[1]
- (d)Group 2 nitrates decompose on heating to form oxides.
- (d)(i)State the trend in thermal stability of the Group 2 nitrates down the group.[1]
- (d)(ii)Identify the other products of the thermal decomposition of Group 2 nitrates.[1]
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Mark scheme
Marking points from the official mark scheme (Oct/Nov 2025). The mark or mark type is shown in brackets.
- [2] (a)(i) M1 nuclear charge increases (across period) AND similar shielding M2 greater / stronger attraction to nucleus
- [2] (a)(ii) M1 Al loses (3) electrons / Al is 3+, and P gains (3) electrons / P is 3- M2 Al (3+) has (one) fewer shell (than P(3-))
- [2] (b)(i) M1 (+)1 (+)2 (+)3 (+)4 (+)5 (+)6 M2 12-14 8-10 — 0-4 0-4
- [1] (b)(ii) they are insoluble
- [1] (c)(i) Na₂O + 2HCl → 2NaCl + H₂O
- [1] (c)(ii) Al₂O₃ + 2NaOH → 2NaAlO₂ + H₂O
- [1] (d)(i) (thermal stability) increases (down the group)
- [1] (d)(ii) NO₂ AND O₂
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