A reaction scheme is shown in Fig. 7.1. The reagents needed for reaction 2 and reaction 3 are stated. Reaction 5 takes place when C2H5NH2 is mixed with compound V. No special conditions are required. [Figure 7.1]
- (a)Identify compound U which contains only three elements.[1]
- (b)Describe the reagents and conditions for reaction 1.[1]
- (c)Identify compound V.[1]
- (d)Complete the equation for reaction 3. CH3COOH + SOC2 → ______[1]
- (e)Identify compound W.[1]
- (f)Describe the conditions for reaction 4.[1]
- (g)Suggest the reagent needed for reaction 6.[1]
- (h)Complete Table 7.1 by adding the reaction numbers, 1, 2, 3, 4, 5 and 6, to the right-hand column. Use the reaction numbers given in Fig. 7.1. Each of the numbers 1, 2, 3, 4, 5 and 6 should be used once only. Table 7.1 type of reaction reaction number(s) hydrolysis addition reduction substitution[4]
- (i)Compare the basicities of C2H5NHCOCH3, C2H5NHC2H5 and NH3. Explain your answer. most basic least basic[4]
This question uses a diagram from the original paper, which isn't shown here. Open the full paper from the past papers archive to see it.
Mark scheme
Marking points from the official mark scheme (Oct/Nov 2024). The mark or mark type is shown in brackets.
- [1] CH3CN / ethanenitrile
- [1] dilute acid / HCl (aq) AND hot / heat (all three components of reagents and conditions required for this mark)
- [1] CH3COCl / ethanoyl chloride
- [1] CH3COOH + SOCl2 → CH3COCl + HCl + SO2
- [1] C2H5Br/C2H5Cl/bromoethane / chloroethane
- [1] heat in ethanol AND under pressure / in sealed tube
- [1] LiAlH4 / lithium aluminium hydride
- [1] hydrolysis: 1
- [1] addition: 2
- [1] reduction: 2, 6
- [1] substitution: 3, 4, 5
- [1] Order of basicity: C2H5NHC2H5 (most basic) > NH3 > C2H5NHCOCH3 (least basic)
- [1] Basicity is linked to the lone pair/p orbital on N AND its ability to accept/donate a proton/H+
- [1] Explanation for C2H5NHC2H5 (amine) being stronger due to +ve inductive effect / electron donating alkyl / R / ethyl group
- [1] Explanation for C2H5NHCOCH3 (amide) being weaker because the lone pair/p orbital on N is delocalised into C=O group
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