The shapes of four different complexes, P, Q, R and S, are shown in Table 5.1. The symbol J represents an atom or ion of a transition element. The symbol L is used to represent a monodentate ligand. [Table 5.1]
- (a)Label one bond angle on each of complexes P, Q, R and S, and identify the size of the angle in degrees.[2]
- (b)Identify the shapes of complexes P, Q, R and S.[2]
- (c)Two L ligands are exchanged with two different monodentate ligands X and Y in each of complexes P, Q, R and S. Identify all the complexes which form new complexes that show geometrical isomerism.[1]
- (d)Three L ligands are exchanged with three different monodentate ligands X, Y and Z in each of complexes P, Q and R. Identify all the complexes which form new complexes that show optical isomerism.[1]
This question uses a diagram from the original paper, which isn't shown here. Open the full paper from the past papers archive to see it.
Mark scheme
Marking points from the official mark scheme (Oct/Nov 2024). The mark or mark type is shown in brackets.
- [1] P: 109 OR 109.5°
- [1] Q: 90° (or 180° if different angle labelled)
- [1] R: 90° (or 180° if different angle labelled)
- [1] S: 180°
- [1] P: tetrahedral
- [1] Q: square planar
- [1] R: octahedral
- [1] S: linear
- [1] Q AND R
- [1] P AND R
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